A solution containing chloride ion was analyzed by the Volhard method. A 50.00 mL sample containing chloride ion was treated with 25.00 mL of 0.2500 M silver nitrate. The precipitated AgCl was removed from the solution by filtration, and 1.00 mL of 0.1000 M Fe3+ was added to the filtrate. This new solution was then titrated with 10.67 mL of 0.2380 M KSCN. What is the concentration of chloride ion in the original solution?

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter4: Stoichiometry: Quantitative Information About Chemical Reactions
Section4.9: Spectrophotometry
Problem 2.1ACP: Excess KI is added to a 100.0-mL sample of a soft drink that had been contaminated with bleach,...
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A solution containing chloride ion was analyzed by the Volhard method. A 50.00 mL sample containing chloride ion was treated with 25.00 mL of 0.2500 M silver nitrate. The precipitated AgCl was removed from the solution by filtration, and 1.00 mL of 0.1000 M Fe3+ was added to the filtrate. This new solution was then titrated with 10.67 mL of 0.2380 M KSCN. What is the concentration of chloride ion in the original solution?
 
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