A carbonate fusion was needed to free the Bi from a 0.6400-g sample containing the mineral eulytite (2Bi2O3. 3SiO2). The fused mass was dissolved in 25.00 mL dilute acid, following which the Bi3+was titrated with 27.00mL of 0.03400M NaH2P04. The reaction is Bi3++ H2PO4-BiPO4(s) + 2H+ Identify: (a) possible chemical indicator for this analysis (b) Calculate the weight percent purity of eulytite (FW=1112.17g/mol) in the sample.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.17QAP
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A carbonate fusion was needed to free the Bi from a 0.6400-g sample containing the mineral eulytite (2Bi2O3. 3SiO2). The fused mass was dissolved in 25.00 mL dilute acid, following which the Bi3+was titrated with 27.00mL of 0.03400M NaH2P04.

The reaction is Bi3++ H2PO4-BiPO4(s) + 2H+

Identify:

(a) possible chemical indicator for this analysis

(b) Calculate the weight percent purity of eulytite (FW=1112.17g/mol) in the sample.

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