Commercial Vanadyl Sulfate (VOSO4) is contaminated with H2SO4 and H2O. A solution was prepared dissolving 0.2447 g of impure VOSO4 in 50.00 mL of water. A spectrophotometric analysis indicated that the The concentration of vanadyl ions, VO2+ (blue) was 0.0243 M. A 5.00 mL sample was passed through a column filled with a cation exchange resin in H+ form, to retain the vanadyl ion and the eluent necessary for its titration 13.03 mL of NaOH 0.02274 M. Calculate the percentage by weight of each component (VOSO4, H2SO4, and H2O) in commercial vanadyl sulfate. (Pm VOSO4, 162.96; H2SO4, 97.94)

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter4: Stoichiometry: Quantitative Information About Chemical Reactions
Section4.9: Spectrophotometry
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Commercial Vanadyl Sulfate (VOSO4) is contaminated with H2SO4 and H2O. A solution was prepared dissolving 0.2447 g of impure VOSO4 in 50.00 mL of water. A spectrophotometric analysis indicated that the The concentration of vanadyl ions, VO2+ (blue) was 0.0243 M. A 5.00 mL sample was passed through a column filled with a cation exchange resin in H+ form, to retain the vanadyl ion and the eluent necessary for its titration 13.03 mL of NaOH 0.02274 M. Calculate the percentage by weight of each component (VOSO4, H2SO4, and H2O) in commercial vanadyl sulfate. (Pm VOSO4, 162.96; H2SO4, 97.94)

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