A chemical engineer is studying the following reaction: HCH,CO,(aq)+CH,NH,(aq) → CH3CO,(aq)+CH3NH;(aq) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound concentration expected change in concentration vessel HCH,CO, 0.94 M t increase OI decrease (no change) CH,NH, 1.01 M t increase OI decrease O (no change) A CH,CO, 0.56 M O t increase OI decrease O (no change) CH,NH, 0.22 M O t increase OI decrease (no change) HCH,CO, 1.05 M t increase I decrease O (no change) CH;NH, 1.12 M O t increase OI decrease O (no change) CH,Co, O t increase 0.45 M I decrease (no change) CH.NH 0.11 M t increase OI decrease O (no change)

Chemistry for Engineering Students
4th Edition
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Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.41PAE: Because calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go...
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reaction
compound
concentration
expected change in concentration
vessel
HCH,CO,
0.94 M
f increase
I decrease
(no change)
CH,NH,
1.01 M
f increase
I decrease
(no change)
A
0.56 M
CH,CO,
f increase
I decrease
(no change)
+
CH;NH,
0.22 M
f increase
I decrease
(no change)
HCH,CO,
1.05 M
f increase
I decrease
(no change)
CH,NH,
1.12 M
↑ increase
I decrease
(no change)
CH,CO,
0.45 M
f increase
decrease
(no change)
+
CH,NH,
0.11 M
↑ increase
O I decrease
O (no change)
HCH,CO,
0.25 M
f increase
I decrease
(no change)
CH,NH,
0.32 M
f increase
I decrease
(no change)
C
CH,CO,
1.25 M
↑ increase
I decrease
(no change)
CH,NH,
0.91 M
↑ increase
O I decrease
(no change)
Transcribed Image Text:reaction compound concentration expected change in concentration vessel HCH,CO, 0.94 M f increase I decrease (no change) CH,NH, 1.01 M f increase I decrease (no change) A 0.56 M CH,CO, f increase I decrease (no change) + CH;NH, 0.22 M f increase I decrease (no change) HCH,CO, 1.05 M f increase I decrease (no change) CH,NH, 1.12 M ↑ increase I decrease (no change) CH,CO, 0.45 M f increase decrease (no change) + CH,NH, 0.11 M ↑ increase O I decrease O (no change) HCH,CO, 0.25 M f increase I decrease (no change) CH,NH, 0.32 M f increase I decrease (no change) C CH,CO, 1.25 M ↑ increase I decrease (no change) CH,NH, 0.91 M ↑ increase O I decrease (no change)
A chemical engineer is studying the following reaction:
+
HCH;CO2(aq)+CH,NH,(aq) → CH;CO,(aq)+CH;NH,(aq)
At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93.
The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. He then measures the composition of the
mixture inside each vessel from time to time. His first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time he measures the compositions.
reaction
compound
concentration
expected change in concentration
vessel
HCH,CO,
0.94 M
f increase
I decrease
(no change)
CH,NH,
1.01 M
f increase
I decrease
(no change)
A
CH,CO,
0.56 M
f increase
I decrease
(no change)
CH,NH,
0.22 M
f increase
OI decrease
O (no change)
HCH,CO,
1.05 M
f increase
I decrease
(no change)
CH,NH,
1.12 M
f increase
I decrease
(no change)
В
CH,CO,
0.45 M
f increase
I decrease
(no change)
CH,NH,
0.11 M
f increase
I decrease
(no change)
Transcribed Image Text:A chemical engineer is studying the following reaction: + HCH;CO2(aq)+CH,NH,(aq) → CH;CO,(aq)+CH;NH,(aq) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound concentration expected change in concentration vessel HCH,CO, 0.94 M f increase I decrease (no change) CH,NH, 1.01 M f increase I decrease (no change) A CH,CO, 0.56 M f increase I decrease (no change) CH,NH, 0.22 M f increase OI decrease O (no change) HCH,CO, 1.05 M f increase I decrease (no change) CH,NH, 1.12 M f increase I decrease (no change) В CH,CO, 0.45 M f increase I decrease (no change) CH,NH, 0.11 M f increase I decrease (no change)
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