A glass / calomel electrode system was found to develop a potential of - 0.0412 V when used I a buffer of pH 6.00; with an unknown solution the potential was observed to be - 0.204 V. Calculate the pH and the [H+] of the unknown. The following cell was employed for the determination of pCrO4: SCE // CrO4 2-(xM) / Ag2CrO4 (s) / Ag (s) Find the pCrO4 if the cell potential is - 0.402 V (E0 Ag/Ag2CrO4 = - 0.316 V ; E SCE = 0.241 V)
A glass / calomel electrode system was found to develop a potential of - 0.0412 V when used I a buffer of pH 6.00; with an unknown solution the potential was observed to be - 0.204 V. Calculate the pH and the [H+] of the unknown. The following cell was employed for the determination of pCrO4: SCE // CrO4 2-(xM) / Ag2CrO4 (s) / Ag (s) Find the pCrO4 if the cell potential is - 0.402 V (E0 Ag/Ag2CrO4 = - 0.316 V ; E SCE = 0.241 V)
Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter23: Potentiometry
Section: Chapter Questions
Problem 23.23QAP: The following cell was found to have a potential of —0.492 V: Ag|AgCl(sat’d)||HA(0.200 M),NaA(0.300...
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A glass / calomel electrode system was found to develop a potential of - 0.0412 V when used I a buffer of pH 6.00; with an unknown solution the potential was observed to be - 0.204 V. Calculate the pH and the [H+] of the unknown.
The following cell was employed for the determination of pCrO4: SCE // CrO4 2-(xM) / Ag2CrO4 (s) / Ag (s) Find the pCrO4 if the cell potential is - 0.402 V (E0 Ag/Ag2CrO4 = - 0.316 V ; E SCE = 0.241 V)
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