The peroxydisulfate ion (S2O8-2) reacts with the iodide ion in aqueous solution via the reaction: S2O82-(aq) + 3I- → 2SO4(aq)+ I3-(aq). An aqueous solution containing 0.050 M of S2O8-2 ion and 0.072 M of I- is prepared, and the progress of the reaction followed by measuring [I-]. The data obtained is given in the table below. Time (s) 0.00 400.0 800.0 1200.0 1600.0 [I‑] (M) 0.072 0.057 0.046 0.037 0.029
The peroxydisulfate ion (S2O8-2) reacts with the iodide ion in aqueous solution via the reaction: S2O82-(aq) + 3I- → 2SO4(aq)+ I3-(aq). An aqueous solution containing 0.050 M of S2O8-2 ion and 0.072 M of I- is prepared, and the progress of the reaction followed by measuring [I-]. The data obtained is given in the table below. Time (s) 0.00 400.0 800.0 1200.0 1600.0 [I‑] (M) 0.072 0.057 0.046 0.037 0.029
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.91PAE
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The peroxydisulfate ion (S2O8-2) reacts with the iodide ion in aqueous solution via the reaction: S2O82-(aq) + 3I- → 2SO4(aq)+ I3-(aq). An aqueous solution containing 0.050 M of S2O8-2 ion and 0.072 M of I- is prepared, and the progress of the reaction followed by measuring [I-]. The data obtained is given in the table below.
Time (s) |
0.00 |
400.0 |
800.0 |
1200.0 |
1600.0 |
[I‑] (M) |
0.072 |
0.057 |
0.046 |
0.037 |
0.029 |
- Determine the average rate of disappearance of I- between 400.0 s and 800.0 s in M/s.
- Determine the average rate of disappearance of I- in the initial 400.0 s in M/s.
- Determine the average rate of disappearance of I- between 1200.0 s and 1600.0 s in M/s.
- Determine the concentration of S2O82- remaining at 400 s in M.
- Determine the concentration of S2O82- remaining at 800 s in M.
- Determine the concentration of S2O82- remaining at 1600 s in M.
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