Consider the following oxidation reaction[Cr(H,O);]²* [Cr(H>O);]³* + e-Calculate the change in CFSE (LFSE) upon oxidation of [Cr(H2O)G]²*.a.The value of Doct is 17400 cm-1 for [Cr(H20)6]²* and 14100 cm- for [Cr(H2O)6]³*b. Is the oxidation favored by CFSE (LFSE)? Explain.

CFSE is the amount of energy gained by the orbital after preferential filling of the orbital by the…

Consider the following oxidation reaction [Cr(H2O)6]²* [Cr(H2O);]³* + e- a. Calculate the change in CFSE (LFSE) upon oxidation of [Cr(H20)c]²*. The value of Doct is 17400 cm-1 for [Cr(H2O)6]²* and 14100 cm-1 for [Cr(H20)s]³+ b. Is the oxidation favored by CFSE (LFSE)? Explain.

Consider the following oxidation reaction [Cr(H2O)6]²* [Cr(H2O);]³* + e- a. Calculate the change in CFSE (LFSE) upon oxidation of [Cr(H20)c]². The value of Doct is 17400 cm-1 for [Cr(H2O)6]² and 14100 cm-1 for [Cr(H20)s]³+ b. Is the oxidation favored by CFSE (LFSE)? Explain.

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 39P

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Question

Consider the following oxidation reaction
[Cr(H,O);]²* [Cr(H>O);]³* + e-
Calculate the change in CFSE (LFSE) upon oxidation of [Cr(H2O)G]²*.
a.
The value of Doct is 17400 cm-1 for [Cr(H20)6]²* and 14100 cm- for [Cr(H2O)6]³*
b. Is the oxidation favored by CFSE (LFSE)? Explain.

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