Draw a tree diagram for H* of CH,FCFH*CHBr,. Note the relative intensities of the peaks at the end of your (Spin of Fluorine = ½; the bromines do NOT couple with H*] tree. The coupling constants are as follows. 100 Hz (J, means the coupling constant between H* and the F bonded to the same carbon). (Ju 1 means the coupling constant between H" and the F bonded to CH,). (Ir-n means the coupling constant between H* and both the H's of CH,F and the H of CHB1, ). 40 Hz 10 Hz 5 Use the rule of 13 to determine a reasonable* molecular formula of a molecule that contains two oxygens and two nitrogens, and has a molecular ion at m/z (mass-to-charge ratio) 174, [Atomic masses: C = 12; H = 1; N = 14; O = 16] *Your formula should have an IHD of less than 6

Organic Chemistry: A Guided Inquiry
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Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
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Draw a tree diagram for H* of CH,FCFH*CHB1,. Note the relative intensities of the peaks at the end of your
[Spin of Fluorine = ½; the bromines do NOT couple with H*]
tree.
The coupling constants are as follows.
Jr-= 100 Hz (J. , means the coupling constant between H* and the F bonded to the same carbon).
(Jup means the coupling constant between H* and the F bonded to CH,).
(Ju-n means the coupling constant between H* and both the H's of CH,F and the H of CHB1; ).
40 Hz
I-n = 10 Hz
5 Use the rule of 13 to determine a reasonable* molecular formula of a molecule that contains two oxygens and two
nitrogens, and has a molecular ion at m/z (mass-to-charge ratio) 174.
[Atomic masses: C = 12; H = 1; N = 14; O=16]
*Your formula should have an IHD of less than 6
Transcribed Image Text:Draw a tree diagram for H* of CH,FCFH*CHB1,. Note the relative intensities of the peaks at the end of your [Spin of Fluorine = ½; the bromines do NOT couple with H*] tree. The coupling constants are as follows. Jr-= 100 Hz (J. , means the coupling constant between H* and the F bonded to the same carbon). (Jup means the coupling constant between H* and the F bonded to CH,). (Ju-n means the coupling constant between H* and both the H's of CH,F and the H of CHB1; ). 40 Hz I-n = 10 Hz 5 Use the rule of 13 to determine a reasonable* molecular formula of a molecule that contains two oxygens and two nitrogens, and has a molecular ion at m/z (mass-to-charge ratio) 174. [Atomic masses: C = 12; H = 1; N = 14; O=16] *Your formula should have an IHD of less than 6
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