Melting or Boiling Point of Hydrocarbons Procedure:  In the picture below, ENCIRCLE the compound that has higher boiling point or melting point for each  of the following pairs.   The longer the hydrocarbon chain or ring size the higher the melting or boiling points. 3. Cyclic structures have higher boiling or melting points than their non-cyclic counterparts with the same  number of carbon atoms. These differences are due in large part to cyclic systems having more rigid  and more symmetrical structures.  Example:  o Propane has higher melting or boiling point compared to ethane because propane has longer  hydrocarbon chain which is composed of 3 carbon atoms in contrast to ethane which is composed  only of 2 carbon atoms. o Cyclopentene has higher melting or boiling point compared to cyclobutene because cyclopentene  has larger ring size which is composed of 5 carbon atoms in contrast to cyclobutene which is  composed only of 4 carbon atoms.  o Cyclopropane has higher melting or boiling point compared to propane because cyclic structures  have higher boiling or melting points than their non-cyclic counterparts with the same number of  carbon atoms. These differences are due in large part to cyclic systems having more rigid and  more symmetrical structures.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter6: Alkanes & Alkenes
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Melting or Boiling Point of Hydrocarbons

Procedure: 

  1. In the picture below, ENCIRCLE the compound that has higher boiling point or melting point for each  of the following pairs.  

  2. The longer the hydrocarbon chain or ring size the higher the melting or boiling points. 3. Cyclic structures have higher boiling or melting points than their non-cyclic counterparts with the same  number of carbon atoms. These differences are due in large part to cyclic systems having more rigid  and more symmetrical structures. 

Example: 

o Propane has higher melting or boiling point compared to ethane because propane has longer  hydrocarbon chain which is composed of 3 carbon atoms in contrast to ethane which is composed  only of 2 carbon atoms.

o Cyclopentene has higher melting or boiling point compared to cyclobutene because cyclopentene  has larger ring size which is composed of 5 carbon atoms in contrast to cyclobutene which is  composed only of 4 carbon atoms. 

o Cyclopropane has higher melting or boiling point compared to propane because cyclic structures  have higher boiling or melting points than their non-cyclic counterparts with the same number of  carbon atoms. These differences are due in large part to cyclic systems having more rigid and  more symmetrical structures.

C. Melting or Boiling Point of Hydrocarbons.
Example:
Cyclooctane
Cyclopentane
1. Нехane
Octane
2. Cyclohexane
Нехane
3. Methane
Ethane
4. Pentane
Cyclooctane
5. Cyclobutane
Cycloheptane
6. 2-Нехene
2-Octene
7. Cyclobutene
Cyclooctene
Transcribed Image Text:C. Melting or Boiling Point of Hydrocarbons. Example: Cyclooctane Cyclopentane 1. Нехane Octane 2. Cyclohexane Нехane 3. Methane Ethane 4. Pentane Cyclooctane 5. Cyclobutane Cycloheptane 6. 2-Нехene 2-Octene 7. Cyclobutene Cyclooctene
2. Суclohexane
Hexane
3. Methane
Ethane
4. Pentane
Cyclooctane
5. Cyclobutane
Cycloheptane
6. 2-Нехene
2-Octene
7. Cyclobutene
Cyclooctene
8. 3-Неptyne
3-Decyne
9. 1-Butene
1-Pentene
10. Cyclononene
1-Nonene
Transcribed Image Text:2. Суclohexane Hexane 3. Methane Ethane 4. Pentane Cyclooctane 5. Cyclobutane Cycloheptane 6. 2-Нехene 2-Octene 7. Cyclobutene Cyclooctene 8. 3-Неptyne 3-Decyne 9. 1-Butene 1-Pentene 10. Cyclononene 1-Nonene
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