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You are a chemist, you know that in the analysis for total hardness, formation of Ca-EDTA complex in the presence of magnesium-calmagite indicator or Mg-Ind complex involves the following process:
Based on the
a. [Mg-EDTA] / {[Mg2+] [EDTA2-]}
b. {[Mg-EDTA] [Ind2-]} / {Mg-Ind] [EDTA2-]}
c. [Mg2+] [EDTA2-]
d. {[Mg2+] [EDTA2-]} / [Mg-EDTA] {[Mg-EDTA]
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- Aecrt5FT-IR technique can be utilized for the analysis of unknown analytes by matching it with__________. Both choices are correct Commercial library/database Reference standardPreparing a standard curve. 1. determine the absorbance max of [FeSCN]2+ it is 448.1 2. determine the concentration of FeSCN2+ in the stock solution. M1V1=M2V2 stock solution: ~0.200 M iron (iii) nitrate in 1M nitric acid intial volume: 0.3mL final volume: 10.3mL volume: 10mL ~0.002M potassium thiocyanate initial volume: 0.3mL final volume: 10.3mL volume: 10mL not sure if this is needed stock solutions: ~0.200M iron (iii) nitrate in 1M nitric acid: 0.207M ~0.002M iron (iii) nitrate in 1M nitric acid: 0.00209M ~0.002M potassium thiocyanate: 0.00193M
- Calculate the Ksp for Ni(OH)2 Ni(OH)2(s) + 2 e- ⟶ Ni(s) + 2OH-(aq); Eo = -0.720 VNi2+(aq) + 2 e- ⟶ Ni(s); Eo = -0.250 V 7.56x1015 1.15x10-8 1.70x10-33 1.32x10-16(9.29 × 105/8)-20.81 = with correct sig figsYou obtained the following raw data when setting up a Bradford standard curve: BSA (mg/ml) Absorbancy 595nm 0 0.225 1 0.310 2 0.420 3 0.510 4 0.610 5 0.720 6 0.810 7 0.915 8 0.950 9 0.980 10 0.990 After blanking against a bradford-dH2O sample, the protein concentration of an unknown sample was determined using the same method and an absorbancy of 0.523 was obtained. Set up a standard curve, excluding outliers (experimental and statistical) and determine the protein concentration in the unknown sample in mg / ml (up to 3 significant figures).
- You determine the acetic acid (HOAc) content of vinegar by titrating with a sodium hydroxide standard solution to a phenolphthalein (an indicator) end point. An approximately 5-mL sample of vinegar is weighed on an analytical balance in a weighing boat and this is found to be 5.0268 g. The standard deviation in making a single weighing is 0.2 mg. The sodium hydroxide must be accurately standardised (this means its concentration must be accurately determined) by titrating known mass of high-purity potassium hydrogen phthalate, and three such titrations give molar concentrations of 0.1167, 0.1163 and 0.1164 mol L-1. A volume of 36.78 mL of sodium hydroxide is used to titrate each sample. The standard deviation of the burette used is 0.02 mL. Calculate the percentage of acetic acid in the vinegar and its standard deviation.You are trying to come up with a drug to inhibit the activity of an enzyme thought to have a role in liver disease. In the laboratory the enzyme was shown to have a Km of 1.0 x 10-6 M and Vmax of 0.1 micromoles/min.mg measured at room temperature. You developed an uncompetitive inhibitor. In the presence of 5.0 x 10-5 M inhibitor, the apparent Vmax was determined to be 0.02 micromoles/min.mg. What is the Ki of the inhibitor?Felodipine calcium channel blocker standard (0.251mg/ml) and felodipine sample (0.245mg/ml) solutions were prepared and injected to the HPLC. The peak area of felodipine standard is 275428 and the sample is 272982. The potency (purity) of felodipine standard is 98.9%. What is the assay percentage of felodipine? a. 102.23 b. 98.71 c. 101.07 d. 100.42
- As part of an analytical chemistry laboratory course, a student measured the Ca2+ content in two water samples, city-supplied drinking water and well-supplied drinking water, using two different analytical methods, flame atomic absorption spectrometry (FAAS) and EDTA complexometric titration. The results of this experiment are given in the table as the mean Ca2+concentration (?¯) and standard deviation (?) in parts per million (ppm). Each sample was measured five times (n=5) by each method. Method City-Supplied Drinking Water (?¯±?x¯±s) Well-Supplied Drinking Water (?¯±?x¯±s) FAAS 57.57±0.68 ppm 64.77±0.70 ppm EDTA titration 58.32±0.96 ppm 65.62±0.97 ppm Method Comparison: For each drinking water sample (city and well), compare the Ca2+ content measured by FAAS and EDTA titration. Calculate the ? value for each sample. Do the methods produce statistically different results at the 95% confidence level when measuring the Ca2+content of the city-supplied drinking water? Do the…Anionic surfactants in wastewater are measured spectrophotometrically as methylene blue active substances (MBAS). A volume of a water sample is first reacted with methylene blue, a cationic dye, in a basic buffered aqueous solution. The resulting solution is agitated after the addition of chloroform. The organic layer is then extracted, and the absorbance is read at 655 nm. A standard calibration curve is produced by plotting absorbance vs. concentration for the concentration range between 0 ppm to 2.50 ppm. The line had the following equation: y = 0.286x + 0.009 a. The limit of surfactant content in Philippine class B water is 300 ppb. If a 5 mL aliquot of a 50 mL water sample had an absorbance of 0.084 after MBAS analysis, is the sampled water body suitable for bathing? Support your answeranalyte concentration(C)(mg/ml) injection volume (ul) elution time (time) peak DAD signal(mAU) caffeine 1 1 4.67 302.85 aspartame 5 1 7.53 15.83 benzoic acid 1 1 8.14 89.98 saccharin 1 1 1.91 84.86 mixture(add everything above with 1:1:1:1 ratio) 1 4.47 69.58 How to get the concentration of the mixture in this case?
