OH но OH OH phthalic acid isophthalic acid pKat = 2.9 pKa2 = 5.4 pKat = 3.7 pKa2 = 4.6 %3D

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter20: Acidity And Pka Of Phenols
Section: Chapter Questions
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Phthalic acid and isophthalic acid have protons on two carboxy groups that can be removed with base. (a) Explain why the pKa for loss of the first proton (pKa1) is lower for phthalic acid than isophthalic acid. (b) Explain why the pKa for loss of the second proton (pKa2) is higher for phthalic acid than isophthalic acid.

OH
но
OH
OH
phthalic acid
isophthalic acid
pKat = 2.9
pKa2 = 5.4
pKat = 3.7
pKa2 = 4.6
%3D
Transcribed Image Text:OH но OH OH phthalic acid isophthalic acid pKat = 2.9 pKa2 = 5.4 pKat = 3.7 pKa2 = 4.6 %3D
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