Problem 135 3295 IR Spectrum (liquid film) 4000 3000 2000 1600 1200 800 00 v (cm") 100 Mass Spectrum 0,5 91 80 UV spectrum 60 0.766 mg / 10 mis path length: 2.00 cm solvent : methanol 134 40 1.0 20 C10 H15N 149 1.5 40 80 120 160 200 240 280 200 250 300 350 m/e 2 (nm) 13C NMR Spectrum (100.0 MHz. CDCI, solution) expansion DEPT CH CHt CH 140 130 opm expansion 140 130 ppm solvent proton decoupled 160 120 80 40 O 8 (ppm) 200 'H NMR Spectrum (400 MHz. CDCI, solution) expansion expansion exchanges with D0 1. 10 1.05 ppm 2.85 2.75 ppm TMS 1. 8 (ppm) 3. 10 6. 7. absorbance 2. yeed eseg jo %

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL1: Infrared Spectroscopy
Section: Chapter Questions
Problem 16CTQ
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Question
Account all numbers peaks immthe IR. In the mass
spectrum, determine degrees of unsaturation and
abel peaks if necessary. Assign all NMR spectra as
compleatly as possible: number of NMR signals,
ntegration,position, chemical shift and splitting.
please explain what goes for what section and write
clearly)
Transcribed Image Text:Account all numbers peaks immthe IR. In the mass spectrum, determine degrees of unsaturation and abel peaks if necessary. Assign all NMR spectra as compleatly as possible: number of NMR signals, ntegration,position, chemical shift and splitting. please explain what goes for what section and write clearly)
Problem 135
3295
IR Spectrum
(liquid film)
4000
3000
1600
2000
v (cm")
1200
800
100
Mass Spectrum
0.5
0.5
91
80
UV spectrum
60
0 766 mg / 10 mis
path length : 2.00 cm
solvent : methanol
134
1.0
40
-20
M*
149
C10 H15N
1.5
250
A (nm)
40
80
120
160
200
240
280
200
300
350
m/e
13C NMR Spectrum
(100.0 MHz. CDCI, solution)
expansion
140
130 ppm
DEPT CH, CH, CH
expansion
140
130 ppm
solvent
proton decoupled
120
80
40
0 8 (ppm)
200
160
'H NMR Spectrum
(400 MHz. CDCI, solution)
expansion
expansion
exchanges
with D,0
1. 10 1.05 ppm
2.85
2.75 ppm
TMS
8.
7.
6.
4
8 (ppm)
10
6.
--
Transcribed Image Text:Problem 135 3295 IR Spectrum (liquid film) 4000 3000 1600 2000 v (cm") 1200 800 100 Mass Spectrum 0.5 0.5 91 80 UV spectrum 60 0 766 mg / 10 mis path length : 2.00 cm solvent : methanol 134 1.0 40 -20 M* 149 C10 H15N 1.5 250 A (nm) 40 80 120 160 200 240 280 200 300 350 m/e 13C NMR Spectrum (100.0 MHz. CDCI, solution) expansion 140 130 ppm DEPT CH, CH, CH expansion 140 130 ppm solvent proton decoupled 120 80 40 0 8 (ppm) 200 160 'H NMR Spectrum (400 MHz. CDCI, solution) expansion expansion exchanges with D,0 1. 10 1.05 ppm 2.85 2.75 ppm TMS 8. 7. 6. 4 8 (ppm) 10 6. --
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