Synthesis of Hexaamminenickel(II) Tetrafluoroborate [Ni(H,0)6]Cl, + 6 NH3 → [Ni(NH3)6]CI, + 6 H,O [Ni(NH3),]Cl, + 2 (NH.)(BF.) → [Ni(NH3)s](BF4)2 + 2 NH,CI

Q: k) The reactions of Group I and Group II with ammonia and chloride ligands give distinctly different…

A: Group I and group II elements are alkali or alkaline earth metals with valency +1 and+2…

Q: K3[Al(C2O4)3]*3H2O is colorless?

A: The given compounds are coordination compounds. Coordination compounds are those compounds which on…

Q: The ligand-field strength also depends on the identity of the central ion, the order being Mn2+ <…

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Q: The formations of [cis-PtCh(NH3)2] and [trans-PtCl½(NH3)2] are different although same ligands are…

A: The formation of above complex cab be explain by trans effect . the trans effect is the effect that…

Q: Which of the following ligands has the weakest field strength? Br- C2O42- NH3 NO2-

A: The spectrochemical series is a list of ligands  arranged in order of their field strength. It is a…

Q: 7. Based on the principles learned in class, order the following coordination complexes from the…

A: Inner orbital complexes are form most stable complexes as compare to outer orbital complexes.  Above…

Q: What is the LFSE for the [Re(H2O)6]3+complex, knowing that ΔΔo =  33000 cm-1 and P= 15000 cm-1 ?

A: Electron configuration of Re is  [Xe] 4f14 5d5 6s2 When the metal Re forms  octahedral complex with…

Q: Question attached

A: All coordination complexes show 18 electron rule.

Q: Write down the IUPAC names of the following complexes and also give stereochemistry and magnetic…

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Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? a.…

A: This question is related to coordination Chemistry. Coordination complexes are the molecules in…

Q: 2. (a) The v(CO) of isoelectronic series [Mn(CO).], [Cr(CO)] and [V(CO) are 2090 cm 2000cm¹ and 1860…

A: All the parts of the questions are answered properly!!

Q: (a) Give systematic names for the following formulas: - [Co(N3)(NH3)s]SO4 - KĄ[Fe(CN);ONO] -…

A: The nomenclature of the coordination complexes are  given below

Q: F3B-NH3

A: Electron deficient molecule tries to gain stability by accepting electrons from bonded or…

Q: Q6.  a) which of these complexes [CoF6]3- and [Co(en)3]3+ Is high spin and how many unpaired…

A: Therefore, [CoF6]3- is a high spin complex , and there are 4 unpaired Electrons present in it.

Q: Of the first-row transition metal complexes of formula [M(NH3)6]3+, which metals are predicted by…

A: Concepts of Jahn-Teller distortion.

Q: Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers. (ii). Calculate…

A: Isomers are those compounds which have same chemical formula but they are different from each other.…

Q: 4. In transition metal complexes, ligands largely interact with metal center via lone pairs:…

A: Ethylenediamine intract metal with two lone pairs. Cl-  Co and CN are monodentate ligand.

Q: CI Ph2(Et)P-Pt-P(Et)Ph2 EtP-Pt-PEt3 MegP-Pt-CI ČI 242 pm ČI 229 pm CI 237 pm Q.3 For the first…

A: Electronic effect: It influence the structure of molecule, reactivity of molecule, or properties of…

Q: Werner prepared two compounds by heating a solution of PtCl₂ with triethyl phosphine, P(C₂H₅)₃,…

A: From given percentage values the moles of each element is calculated as shown below, Pt moles=38.8g…

Q: Please help with this work. Derive the free-ion term (show the steps) and (b) find (ONLY) the ground…

A: This is multi part questions and as per answering guidelines I can only answer first 3 questions if…

Q: The rate of attack on [Co(H 2 O) 6 ]^ 3+ by an entering group Y is nearly independent of Y, with the…

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Q: Which of the following ligands could form chelates? Indicate also the donor atom for each ligand. 1.…

A: As per our guidelines we can solve only first question. Please re-post other questions. Chelating…

Q: Construct a mode | of [Cr (C2 O4 Make sure are linked to donor atoms to indicate how the atorms…

A: The IUPAC name of this compound is Tris Oxalato chromium. It is a coordination compound. there is a…

Q: When water ligands in [Ti(H2O)6]3+ are replaced by CN- ligands to give [Ti(CN)6]3-, the maximum…

A: [Ti(H2O)6]3+ is an octahedral complex and ligand H2O is a weak field ligand. [Ti(CN)6]3- is also an…

Q: Give the electron counts, formal oxidation states, and dn configurations of the following transition…

A: Electron Count The metal and its bonded ligands are all counted as neutral fragments. Thus, a methyl…

Q: Q1 a) which of these complexes [CoFs]³-and [Co(en);]+ Is high spin and how many unpaired electron…

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Q: Explain why [Cu(H2O)6]2+ reacts with 3 2,2’-bipyridine ligands but [Cu(bipy)3]2+ does not react with…

A: The compounds in which a central metal atom is available and joined with groups or molecules…

Q: (a) Write the electronic configuration of Ce3+ ion, and calculate the magnetic moment on the basis…

A: Since you have posted multiple questions, we will answer the first question. Kindly repost the…

Q: The d-electron count of the transition metal center for [((7-CSH3)Ir(CO)2(CH3)] and (Rh(PPH3),CI],…

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Q: Pyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a…

A: Ligands Ligands in the coordinated complex is the ion or neutral molecule that act as the lewis base…

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Q: Indicate the (i) metal oxidation state, (ii) d- electron count, and (iii) the spin only magnetic…

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Q: (b) Give the coordination geometries for each complexes. i. Re (CO) (p-n-C,H) ii. (Ar)W(CO)s iii.…

A: The required work is attached here , kindly find

Q: Give the systematic name for the following coordination compound: [Ru(NH₃)₅(OH₂)]Br₃

A: The naming of coordination compounds can be done by using certain rules. We have  [Ru(NH₃)₅(OH₂)]Br₃…

Q: Which ligand will be dissociated from the [RhCl(OX)(en)(PPH3)] octahedral complex during…

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Q: [Co(CN),(OH;)]* + [Co(NH3)s(NCS)* = [Co(CN):(SCN)]* + [Co(OH,);}** 3. Explain why, in the products…

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Q: The formations of [cis-PtCl2(NH3)2] and [trans-PtCl2(NH3)2] are different although same ligands are…

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Q: Predict the nature, including the correct special isomerisation (i.e. cis/trans) when necessary, of…

A: A question based on trans effect, which is to be accomplished.

Q: When the Ti3+ ion is complexed by ligands X (a neutral molecule) and Y (an anion) it gives…

A: Octahedral species have 6 ligands that come towards central metal atom then, there is d orbital…

Q: About the chelating agents (ligands) classification

A: Here the point 4 is not correct which states that the trivalent chelating agents/ligands have three…

Q: Which of the following oxides is expected to exhibit a strong Jahn-Tell distortion? In all cases,…

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Q: Do ligand exchange to get PotassiumCopperOxalateDihydrate from Tetraamminecopper(II)sulfate, and do…

A: A ligand exchange reaction is a reaction which involves the substitution of one or more ligands in a…

Q: Which ion would you expect to have the largest crystal field splitting, A? strong weak CN,CO NO₂ en…

A: "To get remaining sub-parts solved please repost the complete question and mention the sub-parts to…

Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? Only…

A: The chemical reasons for the chelate effect involve relative enthalpy and entropy changes upon…

Q: 1) What role do the protons play in the transformation of [(SALEN)VO] to [(SALEN)Cl2]?  --- Consider…

A: Protons in the transformation of (SALEN)VO to (SALEN)Cl2:The conjugate base of “salen ligand” which…

Q: The aqueous solution containing [Ni(H2O)6]2+ ions is blue green, those containing [Ni(NH3)6]2+ ions…

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Q: For each of the following complexe ate) and give its magnetic propertie 3. [Fe(NH,),J²* [Cr(CO),J*

A: Concept is based on spectrochemical series. It decides the spin of ligands.

Q: (3) The rate constants for the exchange reaction: [Cr(H2O)sX]? + [*Cr(H2O)6]?[*Cr(H2O)sX] +…

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Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.