The absolute o value for -OCH3 group at the para position is greater than at the meta positionfor the hydrolysis of ethyl benzoate. This implies that the electronic effect of -OCH3 is governedbyA. resonance only at the para positionB. resonance and inductive at the para positionC. inductive only at the meta positionD. resonance and inductive at the meta positionЕ. В and C

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Answered: The absolute o value for -OCH3 group at…

Pushing Electrons

4th Edition

ISBN:9781133951889

Author:Weeks, Daniel P.

Publisher:Weeks, Daniel P.

Chapter2: Resonance Structures

Section: Chapter Questions

Problem 9EQ: There are no important resonance structures for the isopropyl cation CH3C+HCH3 because there are no ...

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QUESTION- Label these spectra attached. Use them to discuss differences in reactant and product spectra that determine/support positive product formation. please no general responses, be specific to peaks in the spectra attached. EXPERIMENT: Synthesis of Benzil - Multi-Step Synthesis Part B benzoin + NH4NO3 ==== benzil ReferencesLehman, J.W. Operational Organic Chemistry: A Problem- Solving Approach to the LaboratoryCourse, 3 rd Ed., Prentice-Hall, Inc: New Jersey, 1999, p. 449.
Repeat Problem 14.36 for [8]annulene. Draw the π MO energy diagram for [10]annulene, similar to those in Figures 14-19 and 14-21. Fill up the orbitals with the appropriate number of π electrons. Based on this diagram, should [10]annulenebe aromatic or antiaromatic? Explain.
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There are no important resonance structures for the isopropyl cation CH3C+HCH3 because there are no in the structure. There are no important resonance structures for dimethyl ether CH3OCH3 because, although there are pushable electrons on the oxygen atom, there is no . There are no important resonance structures for the 5-pentenyl cation H2C=CHCH2CH2C+H2 because the pushable electrons and the receptor are separated by two methylene groups. Thus, the electrons have no way to get to the receptor.
If the group below was on a mono substituted benzene ring, would it be an ortho or para director?
For each of the following substituted benzenes: [1] C6H5Br; [2] C6H5CN; [3] C6H5OCOCH3:a. Does the substituent donate or withdraw electron density by an inductive effect?b. Does the substituent donate or withdraw electron density by a resonance effect?c. On balance, does the substituent make a benzene ring more or less electron rich than benzene itself?d. Does the substituent activate or deactivate the benzene ring in electrophilic aromatic substitution?
Using FMO theory, determine whether a carbanion rearrangement, analogous to the 1,2-hydride shift in Equation D-10, is allowed or forbidden.
Using compounds m-p from image 1please fill in the columns in image 2
Give detailed answer- Provide example of compound that fulfil each criteria below. Explain why-A)1,2-disconnectionB)1,4-disconnectionC)1,5-disconnectionD)1,6-disconnection
Long-range coupling between protons more than two carbon atoms apart is sometimes observed when bonds intervene. An example is found in 1-methoxy-l-buten-3-yne. Not only does the acetylenic proton, Î—a, couple with the vinylic proton Hb, it also couples with the vinylic proton Hc, four carbon atoms away. The data are: Construct tree diagrams that account for the observed splitting patterns of Î—a, Hb, and Hc.
Which is the stronger base: N-methylaniline (C6H5NHCH3) or benzylamine (C6H5CH2NH2). Explain your reasoning, supporting it with appropriate resonance contributors.
Please complete all these reactions in handwritten! I will upvote you!

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