The energy levels (in cm-1) of diatomicanharmonic oscillator are described by thefollowing expression:Ey = (v + 1/2 )we - (v + 1/2 )<Using this equation, derive expressions for theenergies of transition Aɛ for the fundamentalvibration and the 2nd harmonic vibration for adiatomic molecule.

Introduction: Energy level in case of anharmonic oscillator is given as: Ev = (v+1/2)we-…

The energy levels (in cm-1) of diatomic anharmonic oscillator are described by the following expression: Ey = (v + 1/2 )we - (v + 1/2 )< weťe Using this equation, derive expressions for the energies of transition Aɛ for the fundamental vibration and the 2nd harmonic vibration for a diatomic molecule.

The energy levels (in cm-1) of diatomic anharmonic oscillator are described by the following expression: Ey = (v + 1/2 )we - (v + 1/2 )< weťe Using this equation, derive expressions for the energies of transition Aɛ for the fundamental vibration and the 2nd harmonic vibration for a diatomic molecule.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter14: Rotational And Vibrational Spectroscopy

Section: Chapter Questions

Problem 14.64E

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