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- E. explain each step with words on how to get the structure. Step 1: Calculate the Index of Hydrogen Deficiency (IHD). Step 2: Use IR to determine obvious functional groups. Step 3: Use 1H-NMR to determine structural details. Step 4: Confirm the final structure using 13C-NMR.1) what is the struture of B, mechanism for its formation and assigment of the IR and 13C spectra 2) what is the struture of C, mechanism for its formation and assigment of the 1H NMR spectra 3) what is the mechanism of C to D in step 4Describe how the product is purified. 4,4'-DIBROMOBIPHENYL [Biphenyl, 4,4'-dibromo-] Submitted by Robert E. Buckles and Norris G. Wheeler1. Checked by R. S. Schreiber, Wm. Bradley Reid, Jr., and Robert W. Jackson. 1. Procedure In a 15-cm. evaporating dish is placed 15.4 g. (0.10 mole) of finely powdered biphenyl (Note 1). The dish is set on a porcelain rack in a 30-cm. desiccator with a 10-cm. evaporating dish under the rack containing 39 g. (12 ml., 0.24 mole) of bromine. The desiccator is closed, but a very small opening is provided for the escape of hydrogen bromide (Note 2). The biphenyl is left in contact with the bromine vapor for 8 hours (or overnight). The orange solid is then removed from the desiccator and allowed to stand in the air under a hood for at least 4 hours (Note 3). At this point, the product weighs about 30 g. and has a melting point in the neighborhood of 152°. The crude 4,4'-dibromobiphenyl is dissolved in 75 ml. of benzene, filtered, and cooled to 15°. The…
- How to get the wt. sample, g.25. NMR spectra (Figures a, b, c and d) of four isomers are shown. with formula Cl0HuOr Their infrared spectra show strong bands close to 1735 cm'1, do not interpret the aromatic proton region between 7.0 and 7.5 ppm, except to determine the number of protons attached to the aromatic ring. Draw as structures of compounds.Pls help ASAP, thanks! "A compound exhibits a peak at 1685 cm-1 in its IR spectrum. Describe how 13C NMR can be used to identify the functional group."
- A student performed a reaction using 2-methoxyethanol as solvent under acid catalyst. When the solvent was redistilled, a higher boiling fraction (bp=162 °C) was also recovered. The mass spectrum showed a molecular ion at 134 m/z. The H nmr spectrum showed a triplet integrating for 2 at 3.55 ppm, a second triplet integrating for 2 at 3.65 ppm, and a singlet integrating for 3 at 3.4 ppm. Give the structure of the newly formed material that is consistent with this data.An organic lab student carried out the reaction of methylmagnesium iodide with acetone(CH3COCH3), followed by hydrolysis. During the distillation to isolate the product, she forgot to mark the vials she usedto collect the fractions. She turned in a product of formula C4H10O that boiled at 35 °C. The IR spectrum showed onlya weak O¬H stretch around 3300 cm-1, and the mass spectrum showed a base peak at m>z 59. The NMR spectrumshowed a quartet (J = 7 Hz) of area 2 at d 3.5 and a triplet (J = 7 Hz) of area 3 at d 1.3. Propose a structure for thisproduct, explain how it corresponds to the observed spectra, and suggest how the student isolated this compound.SHOW COMPLETE SOLUTIONS Q3. Which isolate has A260/280 ratio of above 2.0?
- 3 The UV−vis spectrum for K[VO(O2)Hheida] shows an absorption at 435 nm (ε = 4 × 102 M−1 cm−1). What phenomenon is presumed to be responsible for this absorption?Give the name/s only (structures not required) of the product for the reaction of (i) A and (ii) B with the reagents listed below. Your answers should be given using A1 -A10 and B1-B10 as indicators.Eg. the product for your first reaction should be stated as A1 = name of product etc. b2h6/h202 n-bromosuccinimide kmno4/oh-A substituted styrene derivative has the following 'H NMR data: 1H NMR (CDCI3, 400 MHz) 8 8.37 (d, 2H), 8.03(d, 2H), 6.86 (dd, 1H), 6.05 (d, 1H), 5.55 (d, 1H). The structure of styrene itself is C6HsCH=CHz. Which styrenederivative is it? which one is it 2-Fluorostyrene2-Nitrostvrene4-Fluorostyrene 3-Hydroxystyrene4-Nitrostyrene