Zinc (Zn) Calibration Curve 0.070 0.060 0.050 0.040 0.030 0.020 0.010 0.000 0.0000 0.0010 0.0020 0.0030 0.0040 0.0050 0.0060 0.0070 [Zn] (M) Estimate the concentration (in M) of an unknown Zn sample that has an absorption of 0.025. O 0.0050 Absorbance
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- Define a molar extinction coefficient and briefly describe how it is measured.Flame Atomic Absorption Spectroscopy (FAAS) method is selected due to its wide applicability for metal ion analysis in drinking water samples. Provide appropriate discussion to determine the concentration of selected heavy metals (Cu and Cr) in the unknown tap water sample.Flame Atomic Absorption Spectroscopy (FAAS) method is selected due to its wide applicability for metal ion analysis in drinking water samples. Discuss how can we determine the concentration of selected heavy metals (Cu and Cr) in the unknown tap water sample.
- The term masking generally refers to: A) Masking generally refers to the transformation of an interfering species into a form that is not detected. B) Selecting samples from which the identity has been masked. This procedure prevents the analyst from prejudging the outcome of the analysis. C) Removing any material that may interfere with an analysis.Calculate the absorbance at 280 nm that is expected for a 17 microM solution of peptide GRAYISH, if a 10-cm cuvette is used. For the extinction coefficient, take into account that e280(Trp) = 5690 M-1 cm-1 and e280(Tyr) = 1280 M-1 cm-1.Potassium dichromate and potassium permanganate have overlapping absorptionspectra in 1M H2SO4 . K2Cr2O7 has an absorption maxima at 440 nm, and KMnO 4 has a band at 545nm (the maximum is actually at 525 nm, but the longer wavelength is generally used whereinterference from K2C2O7 is less). A mixture is analyzed by measuring the absorbance at these twowavelengths with the following results: A 440 =0.405, A 545 =0.712 in a 1-cm cell. The absorbances ofpure solutions of K2Cr2O7 (1x10 -3 M) and KMnO 4 (2.00x10 -4 M) in 1 M H 2 SO 4 , using the same cell gavethe following results: A Cr,440 = 0.374, A Cr,545 = 0.009, A Mn,440 =0.019, A Mn,545 = 0.475. Calculate theconcentrations of dichromate and permanganate in the sample solution.
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