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Concept explainers
a.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangement of atoms in the molecule are said to be isomers of each other.
a.
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Answer to Problem 32PP
Explanation of Solution
For the first isomer structure, all two-carbon atoms are written in a straight chain and the chlorine atom is bonded to one of the carbon atoms as:
There is no other possibility for the different structural formula
b.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangement of atoms in the molecule are said to be isomers of each other.
b.
![Check Mark](/static/check-mark.png)
Answer to Problem 32PP
Isomer I:
Isomer II:
Explanation of Solution
The different structural the arrangement of atoms in the molecule
- All two-carbon atoms are written in a straight chain and two chlorine atoms are bonded to one of the carbon atoms resulting in:
- Interchanging the position of one hydrogen atom at first carbon with one chlorine atom of the second carbon atom.
Isomer I:
Isomer II:
c.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangements of atoms in the molecule are said to be isomers of each other.
c.
![Check Mark](/static/check-mark.png)
Answer to Problem 32PP
Isomer I:
Isomer II:
Explanation of Solution
The different structural arrangement of atoms in the molecule
- All two-carbon atoms are written in a straight chain and three chlorine atoms are bonded to one of the carbon atoms resulting in:
- Interchanging the position of one hydrogen atom at first carbon with one chlorine atom of the second carbon atom.
Isomer I:
Isomer II:
d.
Interpretation: All the constitutional isomers that have molecular formulas
Concept Introduction: The molecules that possess the same molecular formula but differ in the structural arrangements of atoms in the molecule are said to be isomers of each other.
d.
![Check Mark](/static/check-mark.png)
Answer to Problem 32PP
Isomer I:
Isomer II:
Isomer III:
Isomer IV:
Isomer V:
Explanation of Solution
The different structural arrangement of atoms in the molecule
- All six-carbon atoms are written in a straight chain resulting in:
- Five-carbon atoms are written in a straight chain and a methyl group is attached to the second carbon resulting in:
- Five-carbon atoms are written in a straight chain and a methyl group is attached to the third carbon resulting in:
- Four-carbon atoms are written in a straight chain and a methyl group is attached to the second and third carbon resulting in:
- Four-carbon atoms are written in a straight chain and two methyl groups are attached to the second carbon resulting in:
Isomer I:
Isomer II:
Isomer III:
Isomer IV:
Isomer V:
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Chapter 1 Solutions
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
- Which of the following C-C bonds is the shortest? A. в D E Select one: O a. A O b. B O c. C O d. D О е. Еarrow_forwardM A 1.41 In the compounds below, classify each bond as covalent, polar covalent, or ionic: a. NaBr b. NaOH c. NaOCH 3 d. CH3OH e. CH₂O 1.42 Draw structures for all constitutional isomers with the following molecular formulas: a. C₂H₂O b. C₂H60₂ c. C₂H4BR₂ 1.43 For each type of bond below, determine the direction of the expected dipole moment: a. C-O b. C-Mg c. C-N d. C-Li e. C-Cl f. C-Si g. O-H h. N-Harrow_forwardDetermine the geometry around all second-row elements in each compound. :0: a. CH3-C-CH3 b. CHg-Q-CH3 C. TỈNH, Predict the indicated bond angles in each compound. H b. CH₂ C CI a. CH₂=C=C-CI H C. CH3 C CI H d. CH3-C=N:arrow_forward
- How are the molecules in the following pair related? H3C CH₂ CH₂ CI Select one: O A. III O B. II O C. I H₂C-CH CI I. They are isomers. II. They are resonance structures. III. Neither of the choices is correct. CH3arrow_forwardI♥M 96% 6:32 M b N I - 3. Name the compound with the molecular structure shown. CH3 CH. C=C CH, CH, CH,arrow_forwardWhich is the correct representation of formal charge of the Leasing th H-C-N H:6: A. C. H- H H-C H B. D. H-C-N Harrow_forward
- Which of the following bonds is least polar? Select one: а. С-Н b. B-H C. Al-H d. N-H e. P-Harrow_forward4. Provide the molecular formula and draw the skeletal structure for the following molecules. H.. HH N-H H:0: C-H H. H. H H-c-C-H CH3 H2 H3C C. N. H. H. C-H C-H 'N. CH3 CH3 C. H H H. Serotonin Caffeinearrow_forwardFrom the list of skeletal structures (A,B,C,D), choose the best representation of the lewis structure shown: Lewis Structure: H H H-CC- H H Skeletal Structures: В. C. D. Select one: a. Structure A b. Structure B c. Structure C d. Structure D B.arrow_forward
- of How are the molecules in the following pair related? NH H₂C CH3 Select one: A. III OB. II O C. I and I. They are isomers. II. They are resonance structures. III. They are different compounds, not isomers. Clear my choice H₂C OH NHarrow_forwardClassify each bond in the following molecules as σ or л: a. CH3 H b. CH3-C=N C. H& OCH3arrow_forwardD. @ 2 39 F2 Draw charge minimized Lewis structures for the following compounds: W a. HCN S a. What types of intermolecular forces would you predict for each of the compounds above? b. # 3 X command 80 F3 E D $ 4 C 000 888 FA R APR 26 F % ar 20 5 FS T G ^ 6 F6 Y V B H & 7 44 F7 U N * + m 8 J b. IOF I DII FO - M shapes and physical ( 9 K DD F9 0 < I 0 L command F10 P . J - : ; I 4 option F11 { + " [ ? ~~ = 1 I 40 4 112 } ] delete 22 1 1 1 return shiftarrow_forward
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