Organic Chemistry
7th Edition
ISBN: 9780321803078
Author: Bruice, Paula Yurkanis
Publisher: Pearson College Div
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Textbook Question
Chapter 1, Problem 49P
Draw the condensed structure of a compound that contains only carbon and hydrogen atoms and that has
- a. three sp3 hybridized carbons.
- b. one sp3 hybridized carbon and two sp2 hybridized carbons.
- c. two sp3 hybridized carbons and two sp hybridized carbons.
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Chapter 1 Solutions
Organic Chemistry
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.1 - Chlorine has two isotopes, 35Cl and 37Cl; 75.77%...Ch. 1.2 - Prob. 3PCh. 1.2 - a. Write the ground-state electronic configuration...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar? a. b. c. d.Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...Ch. 1.3 - Explain why HCL has a smaller dipole moment than...
Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...Ch. 1.4 - Prob. 15PCh. 1.4 - a. Draw two Lewis structure for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 19PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 21PCh. 1.5 - Draw the following orbitals: a. 3s orbital b. 4s...Ch. 1.6 - Prob. 23PCh. 1.6 - Indicate the kind of molecular orbital (, , , or )...Ch. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.7 - Explain why a bond formed by overlap of s orbital...Ch. 1.9 - Put n number in each of the blanks: a. __ s...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 32PCh. 1.13 - a. What are the relative lengths and strengths of...Ch. 1.13 - Prob. 35PCh. 1.14 - Prob. 36PCh. 1.15 - Which of the bond in a carbon-oxygen double bond...Ch. 1.15 - Would you expect a CC bond formed by sp2sp2...Ch. 1.15 - Caffeine is a natural insecticide found in the...Ch. 1.15 - Prob. 41PCh. 1.15 - Predict the approximate bond angles for a. the CNC...Ch. 1.16 - If the dipole moment of CH3F is 1.847 D and the...Ch. 1.16 - Account for the difference in the shape and color...Ch. 1.16 - What of the following molecules would you expect...Ch. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Draw the condensed structure of a compound that...Ch. 1 - Predict the approximate bond angles: a. the CNH...Ch. 1 - Prob. 51PCh. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - 53. What is the hybridization of each of the...Ch. 1 - Rank the bonds from most polar. a. CO, CF, CN b....Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Prob. 57PCh. 1 - Prob. 58PCh. 1 - Draw the missing lone-pair electrons and assigns...Ch. 1 - a. Which of the indicated bonds in each molecule...Ch. 1 - For each of the following molecules, indicate the...Ch. 1 - Draw a Lewis structure for each of the following:...Ch. 1 - Rank the following compounds from highest dipole...Ch. 1 - In which orbitals are the lone pairs in nicotine?Ch. 1 - Prob. 65PCh. 1 - Prob. 66PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 68PCh. 1 - Which compound has a larger dipole moment: CH3Cl...Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - Explain why CH3Cl has a greater dipole moment than...Ch. 1 - Prob. 73P
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- A single bond between two carbons with different hybridizations has a small dipole. What is the direction of the dipole in the indicated bonds?arrow_forwardDraw the condensed structure of a compound that contains only carbon and hydrogen atoms and that has a. three sp3 hybridized carbons. b. one sp3 hybridized carbon and two sp2 hybridized carbons. c. two sp3 hybridized carbons and two sp hybridized carbons.arrow_forwardDraw electron configuration diagrams for carbon in an unhybridized, sp3 -hybridized state, sp2 -hybridized state, and sp-hybridized state.arrow_forward
- Which of the following statements about an sp hybridized carbon is FALSE? a. It is divalent.b. It forms bonds that are linear.c. It has two p orbitals.d. It always forms triple bonds to carbon.arrow_forwardLabel each carbon atom with the appropriate hybridizationarrow_forwardDraw a molecule that contains at least one sp-hybridized carbon and at least 1 sp2- hybridized carbon. Label those two carbons (one sp- and one sp2-hybridized.)arrow_forward
- Draw a structure of oxindole, with an aromatic ring. Make sure the diagram contains sp3 carbon atom, sp2 carbon atoms, and sp hybridised carbon atoms. The structure should also include a sp2 hybridised heteroatom and a hybridised sp3.arrow_forwarda. What is the hybridization of each N atom in nicotine? b. What is the geometry around each N atom? c. In what type of orbital does the lone pair on each N atom reside? d. Draw a constitutional isomer of nicotine. e. Draw a resonance structure of nicotine.arrow_forwardRizatriptan (trade name Maxalt) is a prescription drug used for the treatment of migraines. (a) How many aromatic rings does rizatriptan contain? (b) Determine the hybridization of each N atom. (c) In what type of orbital does the lone pair on each N reside? (d) Draw all the resonance structures for rizatriptan that contain only neutral atoms. (e) Draw all reasonable resonance structures for the five-membered ring that contains three N atoms.arrow_forward
- How many unhybridized orbitals can you find in an sp2 carbon? How many hybridized orbitals can you find in an sp2 carbon?arrow_forwardOf the following molecule it is true that A. A has trans configuration B. Bhas cis configuration C. A is a trans 3 heptane D . all the abovearrow_forwardIn a tabular format, enumerate 5 molecules where the following atoms are found in: O (sp3-hybridized) Oxygen (sp2-hybridized) Nitrogen (sp2-hybridized) Carbon (sp2-hybridized)arrow_forward
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