Physical Universe
15th Edition
ISBN: 9780077510534
Author: KRAUSKOPF
Publisher: Mcgraw-hill Higher Education (us)
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Textbook Question
Chapter 10, Problem 14E
What energy change would you expect when a molecule breaks up into its constituent atoms?
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An isolated LiCl molecule has its chloride ion
(mass = 35 atomic mass units) at x = 0 pm ,
and its lithium ion (mass = 7 u) at x= 202 pm.
What is the molecule's mass?
depends on the chlorine isotope
O 20 u
42 u
O 28 u
3. Show that in an ideal hexagonal-close-packed (hcp) structure, where the atomic
spheres touch each other, the ratio c/a is given by
:-()*
( 8 \ 1/2
= 1.633.
(The hep structure is discussed in Section 7.)
4 The packing ratio is defined as the fraction of the total volume of the cell that is
filled by atoms. Determine the maximum values of this ratio for equal spheres
located at the points of simple-cubic, body-centered-cubic, and face-centered-cubic
crystals.
The interaction between an atom and a diatomic molecule is described by a ‘repulsive’ potential energy surface. What distribution of vibrational and translational energies among the reactants is most likely to lead to a successful reaction? Describe the distribution of vibrational and translational energies among the products for these most successful reactions.
Chapter 10 Solutions
Physical Universe
Ch. 10 - Prob. 1MCCh. 10 - Prob. 2MCCh. 10 - Prob. 3MCCh. 10 - Prob. 4MCCh. 10 - Prob. 5MCCh. 10 - Prob. 6MCCh. 10 - Prob. 7MCCh. 10 - Prob. 8MCCh. 10 - Prob. 9MCCh. 10 - Prob. 10MC
Ch. 10 - Prob. 11MCCh. 10 - Prob. 12MCCh. 10 - Prob. 13MCCh. 10 - Prob. 14MCCh. 10 - Prob. 15MCCh. 10 - Prob. 16MCCh. 10 - Prob. 17MCCh. 10 - Prob. 18MCCh. 10 - Prob. 19MCCh. 10 - Prob. 20MCCh. 10 - Prob. 21MCCh. 10 - Prob. 22MCCh. 10 - Prob. 23MCCh. 10 - Prob. 24MCCh. 10 - Prob. 25MCCh. 10 - Prob. 26MCCh. 10 - Prob. 27MCCh. 10 - Prob. 28MCCh. 10 - Prob. 29MCCh. 10 - Prob. 30MCCh. 10 - Prob. 31MCCh. 10 - Prob. 32MCCh. 10 - Prob. 33MCCh. 10 - Prob. 34MCCh. 10 - Prob. 35MCCh. 10 - Prob. 36MCCh. 10 - Prob. 37MCCh. 10 - Prob. 38MCCh. 10 - Prob. 39MCCh. 10 - Prob. 40MCCh. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Prob. 3ECh. 10 - Prob. 4ECh. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10ECh. 10 - Prob. 11ECh. 10 - The Bronze Age got its name from the ability of...Ch. 10 - Prob. 13ECh. 10 - What energy change would you expect when a...Ch. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Prob. 23ECh. 10 - Prob. 24ECh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - How many atoms of which elements are present in a...Ch. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Prob. 55ECh. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Prob. 61ECh. 10 - Prob. 62E
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- 1. A model for the potential energy interaction between the two nitrogen atoms in the N2 molecule is proposed that has the form: v(4) = 4E, (4)* - ()'] 12 a. Find the position of the potential minimum and its value there, in terms of o and Eo, respectively. What do these parameters represent physically about the molecule? b. Draw a hand sketch of V(r) showing rmin, V(rmin) and where V crosses the r axis. c. If the atom is disturbed from its equilibrium by a small amount, show that the 7.56. frequency of oscillation is w = d. For molecular nitrogen, the bond length is 1.1 x 10-1°m, the bond (binding) energy is 9.79 eV (15.66 x 10-19 J), the mass is 14 amu = 23.38 x 10-27 kg. In the spectroscopy laboratory, this vibration is measured to be 8.8 x 1013 Hz. Is this a good model for the interatomic potential? (Recall o = 2n times frequency in Hz) where m is the mass of a nitrogen atom.arrow_forwardA + Given that B 7-10- == 13) Suppose that the interaction energy between two atoms is given by E (r) the atoms from a stable molecule with an internuclear distance of 0.3 nm and a dissociation energy of 4 eV, calculate A and B. Also calculate the force require to break the molecule and the critical distance between the nuclei for which this occurs.arrow_forwardSuppose that a semiconductor device is using a 10.51-mg sample of a hypothetical element By, that is doped with 0.8 % (by mole) of another hypothetical element Do. How many Do atoms are in the sample? Atomic Mass: By: 26.274 g/mol Do: 82.183 g/mol 4.64e+18 2.84e+18 3.75e+18 1.93e+18arrow_forward
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