Physical Universe
15th Edition
ISBN: 9780077510534
Author: KRAUSKOPF
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 10, Problem 35MC
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1. A model for the potential energy interaction between the two nitrogen atoms in the
N2 molecule is proposed that has the form:
v(4) = 4E, (4)* - ()']
12
a. Find the position of the potential minimum and its value there, in terms of o and Eo,
respectively. What do these parameters represent physically about the molecule?
b. Draw a hand sketch of V(r) showing rmin, V(rmin) and where V crosses the r axis.
c. If the atom is disturbed from its equilibrium by a small amount, show that the
7.56.
frequency of oscillation is w =
d. For molecular nitrogen, the bond length is 1.1 x 10-1°m, the bond (binding) energy is
9.79 eV (15.66 x 10-19 J), the mass is 14 amu = 23.38 x 10-27 kg. In the spectroscopy
laboratory, this vibration is measured to be 8.8 x 1013 Hz. Is this a good model for
the interatomic potential? (Recall o = 2n times frequency in Hz)
where m is the mass of a nitrogen atom.
2A. Calculate Z and V for sulfur hexafluoride at 75 °C and 15 bar by the following
equations:
a) Truncated virial eqn. 3.39 w/ B = -194 cm³/mol & C = 15,300 cm/mol²
b) Redlich/Kwong eqn.
c) The Soave/Redlich/Kwong equation
d) The Peng/Robinson equation
For sulfur hexafluoride, Tc= 318.7 K, Pc=37.6 bar, Vc= 198 cm³/mol and o = 0.286.
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Which of the folkowing diagrams.correctly shows a molecule of H,SO,?
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B.
H.
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Chapter 10 Solutions
Physical Universe
Ch. 10 - Prob. 1MCCh. 10 - Prob. 2MCCh. 10 - Prob. 3MCCh. 10 - Prob. 4MCCh. 10 - Prob. 5MCCh. 10 - Prob. 6MCCh. 10 - Prob. 7MCCh. 10 - Prob. 8MCCh. 10 - Prob. 9MCCh. 10 - Prob. 10MC
Ch. 10 - Prob. 11MCCh. 10 - Prob. 12MCCh. 10 - Prob. 13MCCh. 10 - Prob. 14MCCh. 10 - Prob. 15MCCh. 10 - Prob. 16MCCh. 10 - Prob. 17MCCh. 10 - Prob. 18MCCh. 10 - Prob. 19MCCh. 10 - Prob. 20MCCh. 10 - Prob. 21MCCh. 10 - Prob. 22MCCh. 10 - Prob. 23MCCh. 10 - Prob. 24MCCh. 10 - Prob. 25MCCh. 10 - Prob. 26MCCh. 10 - Prob. 27MCCh. 10 - Prob. 28MCCh. 10 - Prob. 29MCCh. 10 - Prob. 30MCCh. 10 - Prob. 31MCCh. 10 - Prob. 32MCCh. 10 - Prob. 33MCCh. 10 - Prob. 34MCCh. 10 - Prob. 35MCCh. 10 - Prob. 36MCCh. 10 - Prob. 37MCCh. 10 - Prob. 38MCCh. 10 - Prob. 39MCCh. 10 - Prob. 40MCCh. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Prob. 3ECh. 10 - Prob. 4ECh. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10ECh. 10 - Prob. 11ECh. 10 - The Bronze Age got its name from the ability of...Ch. 10 - Prob. 13ECh. 10 - What energy change would you expect when a...Ch. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Prob. 23ECh. 10 - Prob. 24ECh. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - Prob. 38ECh. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - How many atoms of which elements are present in a...Ch. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Prob. 55ECh. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Prob. 61ECh. 10 - Prob. 62E
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