Concept explainers
Interpretation:
The method of synthesis for the given
Concept introduction:
An outline of the synthesisof polymersusing radical polymerization is as follows:
An alkyl radical is produced that initiates the radical reaction with the monomer. The monomer is repeatedly bonded with the radical chain to form a large molecule. When all the monomers are consumed ortwo radical chains react with each other to terminate the polymerization, the termination ends via combination where two radical chains react with each other to form a big chain, or via disproportionation, where a hydrogen molecule is split into 2 radicals, and each radical chain reacts with a hydrogen radical to form 2 different chains.
Monomers are the small, repetitive building blocks that are bonded together to form a large molecule.
Want to see the full answer?
Check out a sample textbook solutionChapter 10 Solutions
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
- Which of the following ethers can be formed in good yield by condensation of thecorresponding alcohols? For those that cannot be formed by condensation, suggest analternative method that will work.(a) dibutyl ether (b) ethyl n-propyl etherarrow_forwardWrite the structure of the major organic product formed in the reaction of 1-pentene with each of the following: (a) Hydrogen chloride (b) Dilute sulfuric acid (c) Diborane in diglyme, followed by basic hydrogen peroxide (d) Bromine in carbon tetrachloride (e) Bromine in water (f) Peroxyacetic acid (g) Ozone (h) Product of part (g) treated with zinc and water (i) Product of part (g) treated with dimethyl sulfide (CH3)2Sarrow_forward(a) When bromine is added to two beakers, one containing phenyl iso propyl ether and the other containing cyclohexene, the bromine color in both beakers disappears. What observation could you make while performing this test that would allow you to distinguish the alkene from the aryl ether? (b) Write any three methods in detail for the preparation of aldehyde from primary alcohol. (c) State the clemmenson reduction.arrow_forward
- Provide the reagents and solvents (where appropriate) needed to bring about the following transformations. (a) CI (b)arrow_forwardThe natural product halomon could theoretically arise from another naturally occurring compound known as myrcene. To accomplish this, a biochemical process that could deliver the synthetic equivalent of BrCi to all three double bonds would be required. (Chem Comm. 2014, 50, 13725) (a) Using three molar equivalents of BrCL please provide a mechanism to account for the formation of the bracketed structure (you do not need to show stereochemistry in this mechanism) HB (3 equiv) myrcene balomon 8.61a Add curved arrow(s) to show the mechanism steps. Edit Drawing sitsarrow_forwardFor each of the following, write the major product(s) and then draw out each step in the mechanism using curved arrows. Show ALL lone pair electrons and formal charges. Redraw ALL molecules as to show explicitly ALL bonds being broken or formed. Identify the molecular orbital (HOMO) of the nucleophile and the molecular orbital (LUMO) of electrophile involved in the nucleophilic attack. MO diagrams are not necessary. (a). (b). -CHO 2. H₂O 1. LiAlH4 2. H₂O MgBr , etherarrow_forward
- (a) benzene can potentially react with Lewis acid to form new carbon-carbon bond. Propose the starting material and stepwise mechanism to produce new chemical structure which consists of a formula molecule of C11H16.arrow_forward10.16 Design a preparation of each of the following compounds from an alcohol using sulfonate ester methodology. (a) (b) -CH,CH,CH,– SCH, 10.21 (a) According to the mechanism of the reaction shown in Eq. 10.34, what would be the absolute configuration of the alkyl chloride obtained from the reaction of thionyl chloride with (S)-CH,CH,CH,CHD-OH? Explain. (b) According to the mechanism shown in Eqs, 10,36a and 10.36b, what would be the absolute configuration of 2-bromopentane obtained from the reaction of Ph,PBr, with the R enantiomer of 2-pentanol? Explain.arrow_forwardProvide the mechanism of the redica reaction below (b)arrow_forward
- Synthesize from benzene. (Hint: All of these require diazonium ions.)(a) 3-ethylbenzoic acidarrow_forward(a) Illustrate the following name reactions by giving example :(i) Cannizzaro’s reaction(ii) Clemmensen reduction(b) An organic compound A contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollen’s reagent but forms an addition compound with sodium hydrogen sulphite and gives positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acids. Derive the possible structure of compound A.arrow_forward(a) Given and Scara were given a task of synthesising (2-methylprop-1- envl)cyclohexane 2 (A potential TB drug). After a brief discussion with each other, Given proposed Method A to synthesise 2 from cyclohexanecarbaldehyde 1 while Scara proposed Method B that started from hydroxymethylcyclohexane 3. When designing a synthetic route for drug molecule, you have to make sure the synthetic process is as efficient as possible (e.g. few synthetic steps, mostly making one product and more). w 1 THF A Ph Ph Ph B 3 1. PCC 2. isopropyl magnesium vromide 3. H₂SO4 100 °C .OH After analyzing both of these methods, draw any one possible alkene product other than (2-methylprop-1-enyl)cyclohexane 2?arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY