Organic Chemistry (Binghampton University)
Organic Chemistry (Binghampton University)
16th Edition
ISBN: 9781308795010
Author: Carey
Publisher: MCG CUSTOM
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Chapter 10, Problem 21P
Interpretation Introduction

Interpretation:

The product formed in of each of the given reactions is to be determined.

Concept introduction:

Photochemical bromination of alkanes follows the free radical mechanism. Bromination reaction is highly selective. The tertiary hydrogens are more easily abstracted than the secondary or primary hydrogens.

For the addition of hydrogen bromide to alkenes is observed via electrophilic of free radical addition. The reaction of HBr to the double bond in presence of hydrogen peroxide is regioselective and it is opposite to Markovnikov’s rule.

A group 1 metals (Li, Na, K) are reducing agent. The metal in presence of ammonia converts alkyne to alkenes via single electrons transfer.

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