Interpretation:
Each of the given compoundsis to be synthesized from
Concept Introduction:
>The alcohol, in an acidic condition, undergoes dehydration by loss of
The
The conjugate base of alkyne acts as a good nucleophile, and on reaction with a primary
The alkyne, on hydrogenation by a Group 1 metal (lithium, sodium, or potassium) in liquid ammonia, undergoes trans addition of
The alkene, on reaction with hydrogen bromide in the presence of peroxide, undergoes an addition reaction in a way that hydrogen bonds to a more substituted carbon of double bond and bromine bonds to a less substituted carbon of double bond.This is called anti-Markovnikov's rule.
>Alkyne, on halogenation, forms vicinal dihalides.
>The primary alkyl halide on reaction with potassium cyanide undergoes substitution reaction and forms the corresponding alkyl nitrile.
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Organic Chemistry (Binghampton University)
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