CHEMICAL PRINCIPLES (LL) W/ACCESS
7th Edition
ISBN: 9781319421175
Author: ATKINS
Publisher: MAC HIGHER
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 11, Problem 11.31E
(a)
Interpretation Introduction
Interpretation:
The structure and chiral carbon atoms in cocaine have to be identified.
Concept Introduction:
Chiral molecules: Optical isomers that occur with four different groups attached to the same carbon atom are called as chiral carbon atom and the molecules are called as chiral molecules.
(b)
Interpretation Introduction
Interpretation:
The structure and chiral carbon atoms in aflatoxin B2 have to be identified.
Concept Introduction:
Refer to part (a).
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Many naturally occurring compounds contain more than one functional group. Identify the functional groups in the following compounds:(a) Penicillin G is a naturally occurring antibiotic.(b) Dopamine is the neurotransmitter that is deficient in Parkinson’s disease.(c) Capsaicin gives the fiery taste to chili peppers.(d) Thyroxine is the principal thyroid hormone.(e) Testosterone is a male sex hormone.
TRUE OR FALSE
(a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions.
(b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom.
(c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups.
(d) There are two alcohols with the molecular formula C3H8O.
(e) There are three amines with the molecular formula C3H9N.
(f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group.
(g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid.
(h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°.
(i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O.
(j) The molecular formula of the smallest carboxylic…
This question is about the chemistry of alkenes, which are unsaturated hydrocarbons.
(a) State what is meant by the term unsaturated as applied to a hydrocarbon.
(1)
(b) An organic compound, X, is an unsaturated hydrocarbon with molecular formula
CH₂.
(i) Draw the displayed formulae and give the names of two molecules with
molecular formula C₂H, which are E/Z isomers.
(3)
Isomer 1
Isomer 2
Name:
Name:
Chapter 11 Solutions
CHEMICAL PRINCIPLES (LL) W/ACCESS
Ch. 11 - Prob. 11A.1ASTCh. 11 - Prob. 11A.1BSTCh. 11 - Prob. 11A.2ASTCh. 11 - Prob. 11A.2BSTCh. 11 - Prob. 11A.3ASTCh. 11 - Prob. 11A.3BSTCh. 11 - Prob. 11A.4ASTCh. 11 - Prob. 11A.4BSTCh. 11 - Prob. 11A.5ASTCh. 11 - Prob. 11A.5BST
Ch. 11 - Prob. 11A.6ASTCh. 11 - Prob. 11A.6BSTCh. 11 - Prob. 11A.1ECh. 11 - Prob. 11A.2ECh. 11 - Prob. 11A.3ECh. 11 - Prob. 11A.4ECh. 11 - Prob. 11A.5ECh. 11 - Prob. 11A.6ECh. 11 - Prob. 11A.7ECh. 11 - Prob. 11A.8ECh. 11 - Prob. 11A.9ECh. 11 - Prob. 11A.10ECh. 11 - Prob. 11A.11ECh. 11 - Prob. 11A.12ECh. 11 - Prob. 11A.13ECh. 11 - Prob. 11A.14ECh. 11 - Prob. 11A.15ECh. 11 - Prob. 11A.16ECh. 11 - Prob. 11A.17ECh. 11 - Prob. 11A.18ECh. 11 - Prob. 11A.19ECh. 11 - Prob. 11A.20ECh. 11 - Prob. 11A.21ECh. 11 - Prob. 11A.22ECh. 11 - Prob. 11A.23ECh. 11 - Prob. 11A.24ECh. 11 - Prob. 11A.25ECh. 11 - Prob. 11A.26ECh. 11 - Prob. 11A.27ECh. 11 - Prob. 11A.28ECh. 11 - Prob. 11B.1ASTCh. 11 - Prob. 11B.1BSTCh. 11 - Prob. 11B.1ECh. 11 - Prob. 11B.3ECh. 11 - Prob. 11B.4ECh. 11 - Prob. 11B.5ECh. 11 - Prob. 11B.6ECh. 11 - Prob. 11B.7ECh. 11 - Prob. 11B.8ECh. 11 - Prob. 11C.1ASTCh. 11 - Prob. 11C.1BSTCh. 11 - Prob. 11C.1ECh. 11 - Prob. 11C.2ECh. 11 - Prob. 11C.3ECh. 11 - Prob. 11C.4ECh. 11 - Prob. 11C.5ECh. 11 - Prob. 11C.6ECh. 11 - Prob. 11C.7ECh. 11 - Prob. 11C.8ECh. 11 - Prob. 11C.9ECh. 11 - Prob. 11C.10ECh. 11 - Prob. 11C.11ECh. 11 - Prob. 11C.12ECh. 11 - Prob. 11C.13ECh. 11 - Prob. 11C.14ECh. 11 - Prob. 11D.1ASTCh. 11 - Prob. 11D.1BSTCh. 11 - Prob. 11D.2ASTCh. 11 - Prob. 11D.2BSTCh. 11 - Prob. 11D.3ASTCh. 11 - Prob. 11D.3BSTCh. 11 - Prob. 11D.1ECh. 11 - Prob. 11D.2ECh. 11 - Prob. 11D.3ECh. 11 - Prob. 11D.4ECh. 11 - Prob. 11D.5ECh. 11 - Prob. 11D.6ECh. 11 - Prob. 11D.7ECh. 11 - Prob. 11D.8ECh. 11 - Prob. 11D.9ECh. 11 - Prob. 11D.10ECh. 11 - Prob. 11D.11ECh. 11 - Prob. 11D.12ECh. 11 - Prob. 11D.13ECh. 11 - Prob. 11D.14ECh. 11 - Prob. 11D.15ECh. 11 - Prob. 11D.16ECh. 11 - Prob. 11D.17ECh. 11 - Prob. 11D.18ECh. 11 - Prob. 11D.19ECh. 11 - Prob. 11D.20ECh. 11 - Prob. 11D.21ECh. 11 - Prob. 11D.22ECh. 11 - Prob. 11D.23ECh. 11 - Prob. 11D.24ECh. 11 - Prob. 11D.25ECh. 11 - Prob. 11D.26ECh. 11 - Prob. 11D.27ECh. 11 - Prob. 11D.28ECh. 11 - Prob. 11D.29ECh. 11 - Prob. 11D.30ECh. 11 - Prob. 11D.31ECh. 11 - Prob. 11D.32ECh. 11 - Prob. 11D.33ECh. 11 - Prob. 11D.34ECh. 11 - Prob. 11D.35ECh. 11 - Prob. 11D.36ECh. 11 - Prob. 11E.1ASTCh. 11 - Prob. 11E.1BSTCh. 11 - Prob. 11E.2ASTCh. 11 - Prob. 11E.2BSTCh. 11 - Prob. 11E.1ECh. 11 - Prob. 11E.3ECh. 11 - Prob. 11E.4ECh. 11 - Prob. 11E.5ECh. 11 - Prob. 11E.7ECh. 11 - Prob. 11E.8ECh. 11 - Prob. 11E.9ECh. 11 - Prob. 11E.10ECh. 11 - Prob. 11E.11ECh. 11 - Prob. 11E.12ECh. 11 - Prob. 11E.13ECh. 11 - Prob. 11E.14ECh. 11 - Prob. 11E.15ECh. 11 - Prob. 11E.16ECh. 11 - Prob. 11E.17ECh. 11 - Prob. 11E.18ECh. 11 - Prob. 11E.19ECh. 11 - Prob. 11E.20ECh. 11 - Prob. 11E.21ECh. 11 - Prob. 11E.22ECh. 11 - Prob. 11E.23ECh. 11 - Prob. 11E.24ECh. 11 - Prob. 11E.25ECh. 11 - Prob. 11E.26ECh. 11 - Prob. 11E.27ECh. 11 - Prob. 11E.28ECh. 11 - Prob. 11.1ECh. 11 - Prob. 11.2ECh. 11 - Prob. 11.3ECh. 11 - Prob. 11.4ECh. 11 - Prob. 11.5ECh. 11 - Prob. 11.6ECh. 11 - Prob. 11.7ECh. 11 - Prob. 11.8ECh. 11 - Prob. 11.9ECh. 11 - Prob. 11.10ECh. 11 - Prob. 11.11ECh. 11 - Prob. 11.12ECh. 11 - Prob. 11.13ECh. 11 - Prob. 11.14ECh. 11 - Prob. 11.15ECh. 11 - Prob. 11.16ECh. 11 - Prob. 11.17ECh. 11 - Prob. 11.18ECh. 11 - Prob. 11.19ECh. 11 - Prob. 11.20ECh. 11 - Prob. 11.21ECh. 11 - Prob. 11.23ECh. 11 - Prob. 11.24ECh. 11 - Prob. 11.25ECh. 11 - Prob. 11.26ECh. 11 - Prob. 11.27ECh. 11 - Prob. 11.28ECh. 11 - Prob. 11.29ECh. 11 - Prob. 11.30ECh. 11 - Prob. 11.31ECh. 11 - Prob. 11.32ECh. 11 - Prob. 11.33ECh. 11 - Prob. 11.34ECh. 11 - Prob. 11.35ECh. 11 - Prob. 11.36ECh. 11 - Prob. 11.37ECh. 11 - Prob. 11.38ECh. 11 - Prob. 11.41ECh. 11 - Prob. 11.42ECh. 11 - Prob. 11.43ECh. 11 - Prob. 11.44ECh. 11 - Prob. 11.45ECh. 11 - Prob. 11.47ECh. 11 - Prob. 11.49ECh. 11 - Prob. 11.50ECh. 11 - Prob. 11.51ECh. 11 - Prob. 11.52ECh. 11 - Prob. 11.53ECh. 11 - Prob. 11.54ECh. 11 - Prob. 11.55ECh. 11 - Prob. 11.56ECh. 11 - Prob. 11.57E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw the structural isomers of C2H4BrCl and identify which of them has a chiral center.arrow_forward(a) Draw the nine isomers having the formula C7H16 . (Hint: There is one structure with a seven-carbon chain, two structures with six-carbon chains [one is illustrated in the margin above], five structures with a five-carbon chain, and one structure with a fourcarbon chain.)(b) Identify the isomers of C7H16 that are chiral.arrow_forwardExplain each statement in terms of atomic properties:(a) Carbon engages in covalent rather than ionic bonding.(b) Carbon has four bonds in all its organic compounds.(c) Carbon forms neither stable cations, like many metals, norstable anions, like many nonmetals.(d) Carbon bonds to itself more extensively than does any otherelement.(e) Carbon forms stable multiple bondsarrow_forward
- 5. Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group: Name the functional group:arrow_forwardAlcohols A, B, and C all have the composition C4H10O. Molecules of alcohol A contain a branched carbon chain and can be oxidized to an aldehyde; molecules of alcohol B contain a linear carbon chain and can be oxidizedto a ketone; and molecules of alcohol C can be oxidized to neither an aldehyde nor a ketone. Write the Lewis structures of these molecules.arrow_forward(A) A researcher analyzed an unknown solid, extracted from the bark of spruce trees, to determine its percentage composition. An 11.32 mg sample was burned in a combustion apparatus. The carbon dioxide (24.87 mg) and water (5.82 mg) were collected and weighed. From the results of this analysis, Determine: (1) both empirical and molecular formulas if molar mass is 420 g/mol. (ii) How many aromatic rings can this compound contain? (iii)Give the possible chemical name and structure of this compound and hence reasons for your selection.arrow_forward
- If a research paper appeared reporting the structure of a new molecule with formula C2H8 , most chemists would be highly skeptical. Why?arrow_forward5.Write the structural formula of the ester that, when hydrolyzed, would yield the following:(a) methanol and propanoic acid(b) 1-octanol and acetic acid (c) ethanol and butanoic acidarrow_forwardIn an advanced analytical chemistry lab, a team analyzing a compound 'Q' known to be a structural isomer of octane (C8H18). To determine the specific structure of 'Q', a series of spectroscopic analyses are performed. The sequence of the analysis involves: Infrared (IR) spectroscopy, which indicates the absence of functional groups like alcohols, ketones, and carboxylic acids. Nuclear Magnetic Resonance (NMR) spectroscopy, showing signals indicative of only methyl and methylene groups, with no evidence of methine (CH) or quaternary carbon environments. Mass spectrometry (MS), revealing a fragmentation pattern consistent with branched alkane structures. Based on this sequence of analyses, what is the most likely structure of compound 'Q'? Options: A. 2,2,4- Trimethylpentane B. n-Octane C. 2-Methylheptane D. 3-Ethylhexane Don't use chatgpt please provide valuable answerarrow_forward
- (c) Draw the cis- and trans- geometric isomers (if they exist) of: BrCH=CHBrarrow_forward4)arrow_forwardMTBE, Methyl tert-butyl ether, CH3OC(CH3)3, is used as an oxygen source in oxygenated gasolines. MTBE is manufactured by reacting 2-methylpropene with methanol.(a) Using Lewis structures, write the chemical equation representing the reaction.(b) What volume of methanol, density 0.7915 g/mL, is required to produce exactly 1000 kg of MTBE, assuming a 100% yield?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Mass Spectrometry; Author: Professor Dave Explains;https://www.youtube.com/watch?v=hSirWciIvSg;License: Standard YouTube License, CC-BY