The Lewis structures of glycine dipeptide have to be drawn. Concept Introduction: The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

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Answer 1

Question

Chapter 11, Problem 11.44E

(a)

Interpretation Introduction

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

(b)

Interpretation Introduction

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

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MTBE, Methyl tert-butyl ether, CH3OC(CH3)3, is used as an oxygen source in oxygenated gasolines. MTBE is manufactured by reacting 2-methylpropene with methanol.(a) Using Lewis structures, write the chemical equation representing the reaction.(b) What volume of methanol, density 0.7915 g/mL, is required to produce exactly 1000 kg of MTBE, assuming a 100% yield?

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As we’ve discussed, a peptide bond is made when amino group of one amino acid combines with the carboxylic acid group of another amino acid (releasing a water molecule in the process). The C-N bond formed in this process is called a peptide bond. Peptide bonds have a few properties that might be unexpected. a) One property is that the molecular geometries around the C and N atom in the peptide bond are generally planar with bond angles of approximately 120 degrees. Provide an explanation for why the peptide bond would have this property, using Lewis structures, VSEPR theory and/or valence bond theory as appropriate.

Answer 2

Question

Chapter 11, Problem 11.44E

(a)

Interpretation Introduction

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

(b)

Interpretation Introduction

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

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Answer 3

Question

Chapter 11, Problem 11.44E

(a)

Interpretation Introduction

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

(b)

Interpretation Introduction

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

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Answer 4

Question

Chapter 11, Problem 11.44E

(a)

Interpretation Introduction

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

(b)

Interpretation Introduction

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

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Answer 5

Chapter 11, Problem 11.44E

(a)

Interpretation Introduction

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

(b)

Interpretation Introduction

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

Answer 6

Chapter 11, Problem 11.44E

(a)

Interpretation Introduction

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

Answer 7

Chapter 11, Problem 11.44E

(a)

Interpretation Introduction

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

The Lewis structures of glycine dipeptide have to be drawn. Concept Introduction: The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

Solution Summary: The author explains the Lewis structures of glycine dipeptide.

Concept explainers

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

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Chapter 11 Solutions

The Lewis structures of glycine dipeptide have to be drawn. Concept Introduction: The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

Solution Summary: The author explains the Lewis structures of glycine dipeptide.

Concept explainers

Interpretation: The Lewis structures of glycine dipeptide have to be drawn. Concept Introduction: The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

Interpretation: The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.

Want to see the full answer?

Chapter 11 Solutions

Interpretation:

The Lewis structures of glycine dipeptide have to be drawn.

Concept Introduction:

The amide bond that is formed between the carboxyl group of one amino acid and the amino group of another is known as the peptide bond. The peptide bond is called as the amide bond.

Interpretation:

The factor by which resonance structures can account for the restricted rotation and a second resonance structure for the dipeptide has to be given.