Concept explainers
(a)
Interpretation:
The product obtained by the reaction of the given 1-ethylcyclohexene with hydrogen and palladium catalyst has to be identified.
Concept Introduction:
Hydrogenation reaction is nothing but the addition of hydrogen to an
(b)
Interpretation:
The product obtained by the reaction of the given 1-ethylcyclohexene with water in the presence of sulfuric acid has to be identified.
Concept Introduction:
Hydaration reaction is nothing but the addition of water to an alkene. In this reaction two bonds are simultaneously broken, one is carbon-carbon double bond, and second one is
In the addition of water to an unsymmetrical alknene, the hydrogen from water is bonded to the less substituted carbon atom and is called Markovnikov’s rule.
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Principles of General, Organic, Biological Chemistry
- Draw all the alkyl halides with molecular formula C 5H 11Cl formed when pentane (CH 3CH 2CH 2CH 2CH 3) is heated with Cl 2.arrow_forwardReaction of 2-methylpropene with CH3OH in the presence of H2SO4 catalyst yieldsmethyl tert-butyl ether, CH3OC(CH3)3, by a mechanism analogous to that of acid- catalyzed alkene hydration. Write the mechanism, using curved arrows for each step.arrow_forwardDraw the organic products formed when cyclopentene is treated withfollowing reagent. [1] LiAlH4; [2] H2Oarrow_forward
- What happens when (i) chlorobenzene is treated with Cl2/FeCl3,(ii) ethyl chloride is treated with AgNO2, and(iii) 2-bromopentane is treated with alcoholic KOH?arrow_forwardDraw the organic products formed when cyclopentene is treated withfollowing reagent. (CH3)3COOH, Ti[OCH(CH3)2]4, (−)-DETarrow_forwardWhat alkene is the major productwhen 2-bromo-2-methylpentane is treated with sodium ethoxide in ethanol?arrow_forward
- Draw the constitutional isomer formed when the attached alkenes are treated with each set of reagents: [1] H2O, H2SO4; or [2] BH3 followed by H2O2, −OH.arrow_forwarddraw 1-methylcyclopentanolarrow_forwardWhat reagents are needed to convert 1-ethylcyclohexene into (a) 1-bromo-2-ethylcyclohexane; (b) 1-bromo-1-ethylcyclohexane; (c) 1,2-dibromo-1-ethylcyclohexane?arrow_forward
- What alkenes are formed when each alcohol is treated with H 2SO 4? Use the Zaitsev rule to predict the major product.arrow_forwarda. What hydrocarbon with molecular formula C4H10 forms only two monochlorinated products? Both products are achiral. b. What hydrocarbon with the same molecular formula as in part a forms three monochlorinated products? One is achiral and two are chiral.arrow_forwardDraw the structure of the chlorohydrin formed by treating 1-methylcyclohexene with Cl2/H2O.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning