Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 11, Problem 11.25UKC
(a)
Interpretation Introduction
Interpretation:
The IUPAC name for the given
Concept Introduction:
There are about eight rules to be followed while giving IUPAC name for alkene.
- The suffix –ane has to be replaced with the suffix –ene. This is used to indicate the presence of double bond.
- The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
- The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond. In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
- The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
- Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
- In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
- In case if substituents are present in cycloalkene, then the double‑bonded carbon
atoms are numbered 1 and 2 in a direction where the substituent gets the lower number. - If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.
(b)
Interpretation Introduction
Interpretation:
The IUPAC name for the given
Concept Introduction:
IUPAC nomenclature for alkyne:
There are about eight rules to be followed while giving IUPAC name for alkene.
- The suffix –ane has to be replaced with the suffix –yne. This is used to indicate the presence of triple bond.
- The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the triple bond.
- The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the triple bond. In case if the triple bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
- The position of the triple bond has to be given a single number which is lower‑numbered carbon atom that is present in the triple bond.
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Name each alkene:
a. CH3CH=CHCH2CH2CH3
b. CH3CH=CH2
c. CH2CH3
l
CH2=CHCH2CHCH3
ALCOHOLS
1. WHY IS ETHANOL MORE SOLUBLE IN WATER THAN 1-HEXANOL?
2. WHAT IS DENATURED ALCOHOL? AND WHY IS ALCOHOL DENATURED?
ETHER
1. WHY DOES DIETHYL ETHER HAVE MUCH LOWER BOILING POINT THAN 1-BUTANOL?
a. Which of the following names are INCORRECT?(1) But-3-ene(2) 1-bromo-propan-3-ol(3) 2,3-chlorobutaneA. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)
b. What is the IUPAC name for CH3(CH2)2CHO?A. Butan-1-olB. ButanalC. 3-methylpropan-1-ol D. 3-methylpropanal
Chapter 11 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 11.1 - Convert each condensed structure to a complete...Ch. 11.1 - Determine whether each molecular formula...Ch. 11.1 - Give the molecular formula for each of the...Ch. 11.2 - Give the IUPAC name for each alkene. a. (CH3CH2)2C...Ch. 11.2 - Prob. 11.5PCh. 11.2 - Give the structure corresponding to each name. a....Ch. 11.3 - Prob. 11.7PCh. 11.3 - Bombykol is secreted by the female silkworm moth...Ch. 11.3 - Prob. 11.9PCh. 11.3 - Prob. 11.10P
Ch. 11.3 - Prob. 11.11PCh. 11.5 - Prob. 11.12PCh. 11.5 - Prob. 11.13PCh. 11.6 - Prob. 11.14PCh. 11.6 - Prob. 11.15PCh. 11.7 - Prob. 11.16PCh. 11.7 - Prob. 11.17PCh. 11.9 - Prob. 11.18PCh. 11.9 - Draw the structure corresponding to each name. a....Ch. 11.10 - Prob. 11.20PCh. 11.10 - Prob. 11.21PCh. 11.10 - Prob. 11.22PCh. 11 - Prob. 11.23UKCCh. 11 - Prob. 11.24UKCCh. 11 - Prob. 11.25UKCCh. 11 - Prob. 11.26UKCCh. 11 - Answer the following questions about compound A,...Ch. 11 - Prob. 11.28UKCCh. 11 - Prob. 11.29UKCCh. 11 - Prob. 11.30UKCCh. 11 - Prob. 11.31UKCCh. 11 - Prob. 11.32UKCCh. 11 - Prob. 11.33APCh. 11 - Prob. 11.34APCh. 11 - Prob. 11.35APCh. 11 - Prob. 11.36APCh. 11 - Prob. 11.37APCh. 11 - Falcarinol is a natural pesticide found in carrots...Ch. 11 - Prob. 11.39APCh. 11 - Prob. 11.40APCh. 11 - Prob. 11.41APCh. 11 - Prob. 11.42APCh. 11 - Prob. 11.43APCh. 11 - Give the structure corresponding to each IUPAC...Ch. 11 - Leukotriene C4 is a key compound that causes the...Ch. 11 - Prob. 11.46APCh. 11 - Prob. 11.47APCh. 11 - Prob. 11.48APCh. 11 - Prob. 11.49APCh. 11 - Prob. 11.50APCh. 11 - Prob. 11.51APCh. 11 - Prob. 11.52APCh. 11 - Prob. 11.53APCh. 11 - Prob. 11.54APCh. 11 - Prob. 11.55APCh. 11 - Prob. 11.56APCh. 11 - Prob. 11.57APCh. 11 - Draw the products formed in each reaction.Ch. 11 - Prob. 11.59APCh. 11 - Prob. 11.60APCh. 11 - Prob. 11.61APCh. 11 - Prob. 11.62APCh. 11 - Prob. 11.63APCh. 11 - Prob. 11.64APCh. 11 - Prob. 11.65APCh. 11 - Prob. 11.66APCh. 11 - Prob. 11.67APCh. 11 - Prob. 11.68APCh. 11 - Prob. 11.69APCh. 11 - Prob. 11.70APCh. 11 - Prob. 11.71APCh. 11 - Prob. 11.72APCh. 11 - Prob. 11.73APCh. 11 - Prob. 11.74APCh. 11 - Prob. 11.75APCh. 11 - Prob. 11.76APCh. 11 - Prob. 11.77APCh. 11 - Prob. 11.78APCh. 11 - Prob. 11.79APCh. 11 - Prob. 11.80APCh. 11 - Prob. 11.81APCh. 11 - Prob. 11.82APCh. 11 - Prob. 11.83APCh. 11 - Prob. 11.84APCh. 11 - Prob. 11.85APCh. 11 - Prob. 11.86APCh. 11 - Are cis-2-hexene and trans-3-hexene constitutional...Ch. 11 - Prob. 11.88CP
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- Draw the product formed when C6H5N2+Cl− reacts with each compound.arrow_forwarda. What is the chemical structure of biphenyl, circle functional groupsdifferent than alkane, alkene, alkyne? b. Is it polar or nonpolar? _______________________ c. What is its water solubility in g/L? __________________________arrow_forwardExplain why CH3CH2NHCH3 has a higher boiling point than (CH3)3N, even though they have the same molecular weight.arrow_forward
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