Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 11, Problem 29P
Which of the following are chiral?
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Draw the structure of the following molecules:
cis-1,4-dinitrocyclohexane (chair conformation)
bicyclo[2.2.1]heptane
spiro[2.4]heptane
Which of the following compounds has a stereoisomer that is a meso compound? A 2,4-dibromohexane
B 2,4-dibromopentane
C 2,4-dimethylpentane
D 1,3-dichlorocyclohexane
E 1,4-dichlorocyclohexane
F 1,2-dichlorocyclobutane
Is 2-methyl-2,3-pentadiene chiral? What about 2-chloro-2,3-pentadiene?
Chapter 11 Solutions
Organic Chemistry - Standalone book
Ch. 11.1 - Prob. 1PCh. 11.1 - Prob. 2PCh. 11.2 - The two compounds shown differ by a factor of 60...Ch. 11.2 - Prob. 4PCh. 11.2 - Prob. 5PCh. 11.2 - Prob. 6PCh. 11.3 - Prob. 7PCh. 11.3 - Prob. 8PCh. 11.3 - Evaluate 2,3,3-trimethyl-1-butene as a candidate...Ch. 11.4 - After heating a solution of allyl tert-butyl...
Ch. 11.5 - Prob. 11PCh. 11.6 - Prob. 12PCh. 11.8 - Prob. 13PCh. 11.9 - What dienes containing isolated double bonds are...Ch. 11.10 - Prob. 15PCh. 11.10 - Prob. 16PCh. 11.11 - Prob. 17PCh. 11.12 - Dicarbonyl compounds such as quinones are reactive...Ch. 11.12 - 2,3-Di-tert-butyl-1,3-butadiene is extremely...Ch. 11.12 - Methyl acrylate (H2C=CHCO2CH3) reacts with...Ch. 11.13 - Prob. 21PCh. 11.14 - What diene and dienophile could you use to prepare...Ch. 11.14 - Write equations in the synthetic direction for the...Ch. 11.16 - Prob. 24PCh. 11.16 - Prob. 25PCh. 11 - Write structural formulas for each of the...Ch. 11 - Give an acceptable IUPAC name for each of the...Ch. 11 - A certain species of grasshopper secretes an...Ch. 11 - Which of the following are chiral?...Ch. 11 - Describe the molecular geometry expected for...Ch. 11 - Prob. 31PCh. 11 - What compound of molecular formula C6H10 gives...Ch. 11 - Prob. 33PCh. 11 - Prob. 34PCh. 11 - Prob. 35PCh. 11 - Prob. 36PCh. 11 - Identify the more reactive dienophile in each of...Ch. 11 - Prob. 38PCh. 11 - Prob. 39PCh. 11 - Prob. 40PCh. 11 - Prob. 41PCh. 11 - Prob. 42PCh. 11 - Prob. 43PCh. 11 - Prob. 44PCh. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - Show how to prepare each of the following...Ch. 11 - Prob. 48PCh. 11 - Prob. 49PCh. 11 - Prob. 50PCh. 11 - Compound A was converted to compound B by the...Ch. 11 - Suggest reasonable explanations for each of the...Ch. 11 - Prob. 53PCh. 11 - Prob. 54PCh. 11 - Prob. 55DSPCh. 11 - Prob. 56DSPCh. 11 - Prob. 57DSPCh. 11 - Prob. 58DSPCh. 11 - Prob. 59DSP
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- A.) Draw both the condensed and line-bond structure of the following compounds: 1) 3-ethylhexane 2) 1,3-dimethylcyclopentane 3) 1,3-dichloro-3-methylheptane ( Cl- , Chloro branch) 4) bromocyclobutane (Br-, Bromo branch) 5) 5-sec-butylnonane 6) 4-t-butylheptane 7) 4-ethylcycloheptene 8) 4,4-dimethylpent-2-ene 9) 3-chloro-2,7-dimethylnon-4-yne (Cl- Chloro branch) 10) 1-cyclohexylbut-2-ynearrow_forwardDraw all the stereoisomers for the following compounds 1-fluoro-3-methyl cyclopentanearrow_forwardAssign the configuration of the following chiral compounds:arrow_forward
- Draw the structure of the following molecules, for which the name is given. 1. most stable conformation of 1,1-dichloro-2-bromoethane 2. N,N-Dimethylacetamide 3. cyclooctatetraene 4. bicyclo[2.2.1]heptane 5. spiro[2.4]heptanearrow_forwardis diketone cyclohexadiene antiaromatic or nonaromatic?arrow_forwardDraw the compunds below. (2e,4z)-1-bromo-4-methylhexa-2,4-diene (2e,4z)-5-bromo-3-methylhexa-2,4-diene (2z,4e)-1-bromo-4-methylhexa-2,4-diene (2z,4e)-1-bromo-3-methylhexa-2,4-dienearrow_forward
- Determine whether or not the following molecules are chiral: A) CH3CH2CHClCH3 B) CH3CCl2CH3 C) Refer to first photo D) Refer to second photoarrow_forwardWhich is the isomers of hexane arranged according to INCREASING boiling point? 2,3-dimethylbutane < 2,2-dimethylbutane < 2-methylpentane < n-hexane n-hexane < 2,2-dimethylbutane < 2,3-dimethylbutane < 2-methylpentane 2-methylpentane < 2,2-dimethylbutane < 2,3-dimethylbutane < n-hexane 2,2-dimethylbutane < 2,3-dimethylbutane < 2-methylpentane < n-hexane n-hexane < 2,3-dimethylbutane < 2-methylpentane < 2,2-dimethylbutanearrow_forwardCircle all of the chiral centers (i.e., asymmetric carbon atoms) in the following compounds.arrow_forward
- For each of the following molecules, assign whether the molecule is chiral or achiralarrow_forwardDraw the structure of each molecule below and put an asterisk on each tetrahedral stereocenter. i) 3,4-dichlorohexane ii) 3-bromo-1-iodo-5-methylhexane iii) 3-bromo-2,4-dimethylpentanearrow_forwardwhich of the following cannot be distinguished by an infrared spectrum a) resonant hybrids b) tautomers (keto-enol) c) enantiomers d) cis-trans isomersarrow_forward
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