To represent a logical retrosynthesis of the given diol target molecule. Concept introduction: 1 , 2 − diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH 4 , LiAlH 4 , H 2 /Pd , etc., or by dihydroxylation of alkenes . Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne .

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Answer 1

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Chapter 11, Problem 32ASP

Interpretation Introduction

Interpretation: To represent a logical retrosynthesis of the given diol target molecule.

Concept introduction:

1,2− diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH4 , LiAlH4 , H2/Pd , etc., or by dihydroxylation of alkenes.

Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne.

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1) Which of the following sequences this? ОН ? of reagents -OH will accomplish

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Provide the complete mechanism using curved arrow formalism for the reaction of p-isopropxlbenzoic acid undergoing nitration. Tell how many peaks in the 'H and 13C NMR spectrum that would be observed for the final product.

Answer 2

Question

Chapter 11, Problem 32ASP

Interpretation Introduction

Interpretation: To represent a logical retrosynthesis of the given diol target molecule.

Concept introduction:

1,2− diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH4 , LiAlH4 , H2/Pd , etc., or by dihydroxylation of alkenes.

Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne.

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Check out a sample textbook solution

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Answer 3

Question

Chapter 11, Problem 32ASP

Interpretation Introduction

Interpretation: To represent a logical retrosynthesis of the given diol target molecule.

Concept introduction:

1,2− diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH4 , LiAlH4 , H2/Pd , etc., or by dihydroxylation of alkenes.

Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne.

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Answer 4

Question

Chapter 11, Problem 32ASP

Interpretation Introduction

Interpretation: To represent a logical retrosynthesis of the given diol target molecule.

Concept introduction:

1,2− diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH4 , LiAlH4 , H2/Pd , etc., or by dihydroxylation of alkenes.

Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne.

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Answer 5

Chapter 11, Problem 32ASP

Interpretation Introduction

Interpretation: To represent a logical retrosynthesis of the given diol target molecule.

Concept introduction:

1,2− diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH4 , LiAlH4 , H2/Pd , etc., or by dihydroxylation of alkenes.

Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne.

Answer 6

Chapter 11, Problem 32ASP

Interpretation Introduction

Interpretation: To represent a logical retrosynthesis of the given diol target molecule.

Concept introduction:

1,2− diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH4 , LiAlH4 , H2/Pd , etc., or by dihydroxylation of alkenes.

Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne.

Answer 7

Chapter 11, Problem 32ASP

Interpretation Introduction

Interpretation: To represent a logical retrosynthesis of the given diol target molecule.

Concept introduction:

1,2− diols can be formed from diketones by reducing the two carbonyl groups using a variety of reducing agents such as NaBH4 , LiAlH4 , H2/Pd , etc., or by dihydroxylation of alkenes.

Thus, a vicinal diol can be prepared from an alkene starting material, and a trans alkene can be prepared from an alkyne.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11.1 - Prob. 1CC Ch. 11.1 - Prob. 2CC Ch. 11.2 - Prob. 1LTS Ch. 11.2 - Prob. 3PTS Ch. 11.3 - Prob. 2LTS Ch. 11.3 - Prob. 6ATS Ch. 11.4 - Prob. 3LTS Ch. 11.4 - Prob. 7PTS Ch. 11.4 - Prob. 8ATS Ch. 11.5 - Prob. 4LTS

Solution Summary: The author explains that diols can be formed from diketones by reducing the two carbonyl groups, or by dihydroxylation of alkenes.

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Chapter 11 Solutions