ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
10th Edition
ISBN: 9781260001099
Author: Carey
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 11, Problem 47P
Show how to prepare each of the following compounds from propene and any necessaryorganic or inorganic reagents:
a) Allyl bromide
b)
c)
d)
e)
f) Allyl alcohol
g)
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
True/False question and multiple choice. explanatiom not needed. just give the answer. thank you.
a) Williamson synthesis of ether requires un hindered alkyl halide and hindered alcohol
b) NaBH4 can reduce a carboxylic acid to primary alcohol
c) Conjugated diene reacts with which among the following to form a cyclohexene?1) Phenol2) Dienophile3) Hexane4) Tribromo phenol
d)
1,3 -cyclohexadiene is
1. aromatic
2. has higher heat of hydrogenation than cyclohexene
3. is a good dienopile
4. has lower heat of hydrogenation than cyclohexene
Synthesize the following molecule from benzene and compounds with 4 carbons or less add any inorganic reagent you want.
Show how to convert propene to this compound , using any inorganic reagents as necessary.
Q.) Propanoic acid
Chapter 11 Solutions
ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
Ch. 11.1 - Prob. 1PCh. 11.1 - Prob. 2PCh. 11.2 - The two compounds shown differ by a factor of 60...Ch. 11.2 - Prob. 4PCh. 11.2 - Prob. 5PCh. 11.2 - Prob. 6PCh. 11.3 - Prob. 7PCh. 11.3 - Prob. 8PCh. 11.3 - Evaluate 2,3,3-trimethyl-1-butene as a candidate...Ch. 11.4 - After heating a solution of allyl tert-butyl...
Ch. 11.5 - Prob. 11PCh. 11.6 - Prob. 12PCh. 11.8 - Prob. 13PCh. 11.9 - What dienes containing isolated double bonds are...Ch. 11.10 - Prob. 15PCh. 11.10 - Prob. 16PCh. 11.11 - Prob. 17PCh. 11.12 - Dicarbonyl compounds such as quinones are reactive...Ch. 11.12 - 2,3-Di-tert-butyl-1,3-butadiene is extremely...Ch. 11.12 - Methyl acrylate (H2C=CHCO2CH3) reacts with...Ch. 11.13 - Prob. 21PCh. 11.14 - What diene and dienophile could you use to prepare...Ch. 11.14 - Write equations in the synthetic direction for the...Ch. 11.16 - Prob. 24PCh. 11.16 - Prob. 25PCh. 11 - Write structural formulas for each of the...Ch. 11 - Give an acceptable IUPAC name for each of the...Ch. 11 - A certain species of grasshopper secretes an...Ch. 11 - Which of the following are chiral?...Ch. 11 - Describe the molecular geometry expected for...Ch. 11 - Prob. 31PCh. 11 - What compound of molecular formula C6H10 gives...Ch. 11 - Prob. 33PCh. 11 - Prob. 34PCh. 11 - Prob. 35PCh. 11 - Prob. 36PCh. 11 - Identify the more reactive dienophile in each of...Ch. 11 - Prob. 38PCh. 11 - Prob. 39PCh. 11 - Prob. 40PCh. 11 - Prob. 41PCh. 11 - Prob. 42PCh. 11 - Prob. 43PCh. 11 - Prob. 44PCh. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - Show how to prepare each of the following...Ch. 11 - Prob. 48PCh. 11 - Prob. 49PCh. 11 - Prob. 50PCh. 11 - Compound A was converted to compound B by the...Ch. 11 - Suggest reasonable explanations for each of the...Ch. 11 - Prob. 53PCh. 11 - Prob. 54PCh. 11 - Prob. 55DSPCh. 11 - Prob. 56DSPCh. 11 - Prob. 57DSPCh. 11 - Prob. 58DSPCh. 11 - Prob. 59DSP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- a) Draw the structure of alkene and proposed reagent(s) used to prepare the product in Reaction A. Draw the reaction mechanism for first image b) Predict the molecular structure of the major product(s) of Reaction B and C with second image c) Rank the following compounds from the lowest to highest boiling point. Explain your answer briefly. A: 1-Butanoic acid; B: 1- Butanol; C: 1-Butane d) Draw any three alcohol isomers with molecular formula of C4H10O. e) Based on isomer structures you drawn in part (d), draw the final oxidation product(s) (by KMnO4/H+) of any two isomer, respectively.arrow_forwardShow how to convert propene to this compound , using any inorganic reagents as necessary. Q.) Propenalarrow_forwardShow how to convert propene to each of these compounds, using any inorganic reagents as necessary. a. Propane b.1,2-Propanediol c. 1-Propanol d. 2-Propanol e. Propanal f. Propanone g. Propanoic acid h. l-Bromo-2-propanol i. 3-Chloropropene j. 1,2,3-Trichloropropane k. 1-Chloropropane l. 2-Chloropropane m. 2-Propen-1-ol n. Propenalarrow_forward
- When toluene is treated with sulfuric and nitric acids under special conditions, three nitro (NO2) groups are substituted for hydrogens at the 2, 4 and 6 positions on the ring (the next section discusses why the 2, 4, and 6 positions are substituted). The product is a highly explosive substance called 2,4,6-trinitrotoluene. This subastance is commonly known by a three letter name. What is it?arrow_forwardSynthesize the following compound from benzene and any other reagentarrow_forward1. An unsaturated hydrocarbon reacts with acidic KMnO4 to give isobutyric acid as the only organic product. The unsaturated hydrocarbon is most probably: a. none of these b. 2,2-dimethyl-3-hexene c. 3,4-dimethyl-3-hexene d. 4-methyl-2-hexene e. 2,5-dimethyl-3-hexene 2. Which of the ff. halides will most probably react via an SN1 mechanism? a. CH2=CHCl b. CH2=CHCH2CH2Cl c. CH3CH=CHCH2Cl d. CH3Cl 3. Which of the following will decolorize potassium permanganate solution at room temperature? a. 2-bromobutane b. 1-propanol c. chlorobenzene d. 1-hexynearrow_forward
- Answer the following questions involving organic synthesis: a.) Propose a forward synthesis of an alkyne from an alkene starting material. b.) Develop a forward synthesis of an epoxide from 1-chloropropane. c.) Write a reasonable forward synthesis for the conversion of 2-bromopentane to ethyl methyl ether. d.) Write any reaction with an alkene that occurs via a syn addition and draw its transition state. e.) Write any reaction with an alkene that occurs via an anti addition and draw its transition state. f.) Define Markovnikov’s rule and write out two reactions: one that is a Markovnikov addition and another that is an anti-Markovnikov pathway.arrow_forwardShow how to convert propene to this compound , using any inorganic reagents as necessary. Q.) 1-Bromo-2-propanolarrow_forwardWrite a stepwise mechanism for each of the following reactions. Explainwhy a more stable alkyne (but-2-yne) is isomerized to a less stablealkyne (but-1-yne), but under similar conditions, 2,5-dimethylhex-3-yneforms 2,5-dimethylhexa-2,3-diene.arrow_forward
- Starting with cyclohexanone, show how to prepare these compounds. In addition to the given starting material, use any other organic or inorganic reagents as necessary. Q.) Cyclohexenearrow_forwardDevising a Synthesis from an Alkene Devise a synthesis of 1-ethoxy-2-methylcyclohexane from 1-methylcyclohexene.arrow_forwardFrom benzene and compounds of 4 carbons or less and any reagents you want; synthesize the following compound.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
How to Design a Total Synthesis; Author: Chemistry Unleashed;https://www.youtube.com/watch?v=9jRfAJJO7mM;License: Standard YouTube License, CC-BY