ORGANIC CHEMISTRY WILEYPLUS ACCESS>I<
4th Edition
ISBN: 9781119850151
Author: Klein
Publisher: WILEY
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Chapter 1.11, Problem 27ATS
Interpretation Introduction
Interpretation: The geometry of silicon atom in trimethylhydroxysilane needs to be determined.
Concept Introduction: The arrangement of electron pairs is identified according to VSEPR (Valence Shell Electron Pair Repulsion) theory wherein all the electron pairs are aligned in such a way that they are at maximum distance from each other. The structure of every molecule in VSEPR is explained by considering the steric number (combination of lone pairs and
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Part A
Benzene is an organic chemical compound with the molecular formula C6H6. In the benzene molecule, carbon atoms form a ring with alternating single and double bonds connecting them. Thus, each
individual carbon atom forms one o bond with another carbon atom and one o and one bond with another carbon atom. Each carbon atom also forms one o bond with a hydrogen atom.
H
H
sp³-sp³
H
Identify which types of orbitals overlap to form the bonds between the atoms in a benzene molecule.
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sp-sp
sp² - sp²
р-р
Bonds formed
Carbon-carbon o bond
Carbon-carbon 7 bond
H-C
Carbon-hydrogen o bond
C=C
C-H
H
Type of orbitals involved
P Pearson
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2.
Name the following hydrocarbon. Predict the hybridization
(sp³, sp2, o sp) in the asteroid carbon. Mention the
shape and bond angle
A 3D representation of a cyclohexane (C6H₁2) molecule, a
cyclic compound used in the manufacture of nylon and found
in the distillation ofpetroleum, is shown.
What is the molecular geometry around each carbon atom?
molecular geometry:
9
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C
D
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OH
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Chapter 1 Solutions
ORGANIC CHEMISTRY WILEYPLUS ACCESS>I<
Ch. 1.2 - Prob. 1LTSCh. 1.2 - Prob. 2ATSCh. 1.2 - Prob. 2LTSCh. 1.3 - Prob. 3LTSCh. 1.3 - Prob. 4PTSCh. 1.3 - Prob. 5PTSCh. 1.4 - Prob. 4LTSCh. 1.4 - Prob. 7PTSCh. 1.4 - Prob. 8PTSCh. 1.4 - Prob. 9ATS
Ch. 1.5 - Prob. 5LTSCh. 1.5 - Prob. 10PTSCh. 1.5 - Prob. 11ATSCh. 1.5 - Prob. 12ATSCh. 1.6 - Prob. 6LTSCh. 1.6 - Prob. 14ATSCh. 1.7 - Prob. 7LTSCh. 1.7 - Prob. 17ATSCh. 1.10 - Prob. 18CCCh. 1.10 - Prob. 20CCCh. 1.10 - Prob. 8LTSCh. 1.10 - Prob. 21PTSCh. 1.10 - Nemotin is a compound that was first isolated from...Ch. 1.10 - Prob. 23CCCh. 1.11 - Prob. 9LTSCh. 1.11 - Prob. 24PTSCh. 1.11 - Prob. 25PTSCh. 1.11 - Prob. 26PTSCh. 1.11 - Prob. 27ATSCh. 1.12 - Prob. 10LTSCh. 1.12 - Prob. 29ATSCh. 1.13 - Prob. 11LTSCh. 1.13 - Prob. 31ATSCh. 1 - Prob. 32PPCh. 1 - Prob. 33PPCh. 1 - Prob. 34PPCh. 1 - Prob. 35PPCh. 1 - Prob. 36PPCh. 1 - Prob. 37PPCh. 1 - Prob. 38PPCh. 1 - Prob. 39PPCh. 1 - Prob. 40PPCh. 1 - Prob. 41PPCh. 1 - Prob. 42PPCh. 1 - Prob. 44PPCh. 1 - Prob. 45PPCh. 1 - Prob. 46PPCh. 1 - Prob. 47PPCh. 1 - Prob. 48PPCh. 1 - Prob. 49PPCh. 1 - Prob. 50PPCh. 1 - Prob. 51PPCh. 1 - Prob. 52PPCh. 1 - Prob. 53PPCh. 1 - Prob. 54PPCh. 1 - Nicotine is an addictive substance found in...Ch. 1 - Prob. 56PPCh. 1 - Prob. 57PPCh. 1 - Prob. 59PPCh. 1 - Prob. 63ASPCh. 1 - Prob. 64ASPCh. 1 - Prob. 66ASPCh. 1 - Prob. 69ASPCh. 1 - Prob. 71ASPCh. 1 - Prob. 72ASPCh. 1 - Prob. 75IP
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- Use the VSEPR model to predict the bond angles around each central atom in the following Lewis structures (benzene rings are frequently pictured as hexagons, without the letter for the carbon atom at each vertex). Note that the drawings do not necessarily depict the bond angles correctly.arrow_forwardFormamide, HC(O)NH2, is prepared at high pressures from carbon monoxide and ammonia, and serves as an industrial solvent (the parentheses around the O indicate that it is bonded only to the carbon atom and that the carbon atom is also bonded to the H and the N atoms). Two resonance forms (one with formal charges) can be written for formamide. Write both resonance structures, and predict the bond angles about the carbon and nitrogen atoms for each resonance form. Are they the same? Describe how the experimental determination of the HNH bond angle could be used to indicate which resonance form is more important.arrow_forwardWrite Lewis structures for the Cis -trans isomers of CH3CH = CHCl.arrow_forward
- In Chapter 6, we study a group of organic cations called carbocations. Following is the structure of one such carbocation, the tert-butyl cation. (a) How many electrons are in the valence shell of the carbon bearing the positive charge? (b) Using VSEPR, predict the bond angles about this carbon. (c) Given the bond angle you predicted in (b), what hybridization do you predict for this carbon?arrow_forwardKetene, C2H2O, is a reactant for synthesizing cellulose acetate, which is used to make films, fibers, and fashionable clothing. (a) Write the Lewis structure of ketene. Ketene does not contain an OH bond. (b) Identify the electron-region geometry and the molecular geometry around each carbon atom and all the bond angles in the molecule. (c) Identify the hybridization of each carbon and oxygen atom. (d) Is the molecule polar or nonpolar? Use appropriate data to support your answer.arrow_forward2) Based on valence bond theory, which statement best describes the electron geometry and hybridization of the central atom(s) in acetylene HCCH? A) The electron geometry of the 2 carbons in acetylene is linear with a sp hybridization. B) The electron geometry of the 2 carbons in acetylene is trigonal planar with a sp2 hybridization. C) The electron geometry of the 2 carbons in acetylene is tetrahedral with a sp3 hybridization.arrow_forward
- Draw a line-bond structure for propene, CH3CH=CH2. Indicate the hybridization of the orbitals on each carbon, and predict the value of each bond angle.arrow_forwardA 3D representation of a cyclohexane (C,H12) molecule, a O H cyclic compound used in the manufacture of nylon and found in the distillation ofpetroleum, is shown. What is the molecular geometry around each carbon atom? molecular geometry:arrow_forwardFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name acetic acid dimethyl ether compound hypobromous acid formula or Lewis structure H :0: H-C-C-O-H H H H-C-0-C H H H T HBrO | H Between molecules of the compound? yes O O no O yes no yes hydrogen-bonding force no Between molecules of the compound and molecules of water? O O yes no yes no yes no Xarrow_forward
- 2a) The molecule ethene (or ethylene), which has the molecular formula C₂H4, contains two carbon atoms with planar geometry. Construct a model of ethene by first connecting two black balls with two springs. Use four short sticks and four yellow balls to complete the structure. Sketch a perspective representation (a three dimensional drawing) of the structure. 2b) What is the C=C-H bond angle in ethene?arrow_forwardBuild a model of methane – - What are the approximate bond lengths and bond angles in methane?- What is the name given to the shape of methane?- Explain what is meant by the term ‘sp3 hybridisation’.- Use wedge and dash bonds to draw the shape of the model you have made.arrow_forwardThis is the shape of the sp hybrid carbons in this compound. tetrahedral trigonal planar linear square This is the General Formula of alkanes, where n is the number of C. CnH2n CnH2n-2 CnH2n+2 CnH2n-4 This class of organic compounds is saturated with only carbon-carbon single bonds. O Alkynes Alkenes Alkanes Arenes O Oarrow_forward
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