(a)
Interpretation:
The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.
Concept introduction:
The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective
(b)
Interpretation:
The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.
Concept introduction:
The reaction of secondary alcohols with PCC leads to the formation of
(c)
Interpretation:
The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.
Concept introduction:
The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with
(d)
Interpretation:
The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.
Concept introduction:
The reaction of secondary alcohols with
The conversion of an alcohol into an alkyl bromide is done by
The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with
(e)
Interpretation:
The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.
Concept introduction:
The conversion of an alcohol into an alkyl bromide is done by
The reaction of an alcohol with
(f)
Interpretation:
The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.
Concept introduction:
The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by
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Chapter 11 Solutions
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
- Write the condensed structural formula of the following alcohols and their classification. A. 2,2-dimethyl-1-hexanolB. 3-ethyl-2-pentanol C. 3,5-dimethylcylohexanolarrow_forward4. Draw structures for the following alcohols. a. butane-1,2-diol 2,4-dimethylcyclopentanol C. b. d. 3-ethyl-4-methyloctan-1-ol propane-1,2,3-triolarrow_forwardThe dehydration of an alcohol produces which organic functional group and steam? a. alkyne b. aldehyde c. alkene d. ketone e. carboxylic acid and an alcoholarrow_forward
- 4. MAINIDEA Compare and contrast alkyl halides and aryl halides. 5. Draw structures for the following molecules. a. 2-chlorobutane c. 1,1,1-trichloroethane b. 1,3-difluorohexane d. 1-bromo-4-chlorobenzene 6. Define functional group and name the group present in each of the following structures. Name the type of organic compound each substance represents. a. CH3CH,CH2OH b. CH;CH,F c. CH;CH,NH2 7. Evaluate How would you expect the boiling points of propane and 1-chloropropane to compare? Explain your answer. d. CH3C- OH 8. Interpret Scientific Illustrations Examine the pair of substituted hydrocarbons illustrated at right, and decide whether it represents a pair of optical isomers. Explain your answer.arrow_forwardEach of the following alcohols is named incorrectly. However, the names give correct structural formulas. Draw structural formulas for the compounds, and the write the correct IUPAC name for each alcohol. a. 3-Ethyl-2-butanol b. 3,4-Pentanediol c. 3-Methyl-3-butanol thul L-butanolarrow_forwardConsider the structure of cyclohexene, if it undergoes epoxidation followed by exposure to water, which of the following final product is formed? a. Cyclohexan-1,2,-diol b. Cyclohexane c. Cyclohexanone d. Hexan-1,-6-dioic acidarrow_forward
- Give the reagent and the reaction conditions that would distinguish between the following compounds. Write the chemical reactions. a. benzene and cyclohexane b. 1-propene and 1-propyne c. ethyl benzene and acetylene d. 2-butene and butanearrow_forwardA student was given the structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed. a. 4-bromo-3-pentanol b. 2,2-dimethyl-4-ethylheptane c. 5-methylcyclohexanol d. 1,1-dimethyl-2-cyclohexanol e. 5-(2,2-dimethylethyl)nonane f. isopentylbromide g. 3,3-dichlorooctane h. 5-ethyl-2-methylhexane i. 1-bromo-4-pentanol j. 3-isopropyloctane k. 2-methyl-2-isopropylheptane l. 2-methyl-N,N-dimethyl-4-hexanaminearrow_forwardIdentify the organic functional groups and reaction type for the following reaction if only the major product is shown.The reactant is a(n)a. alkyneb. etherc. alkened. alcohole. aromaticThe product is a(n)a. tertiary alcoholb. primary alcoholc. aldehyde d. ethere. secondary alcoholThe reaction type is :a. hydrolysisb. hydrationc. reduction (hydrogenation)d. dehydratione. oxidationI got alkene, tertiary alcohol, and hydrolysis, but I missed one of them. What are the correct answers?arrow_forward
- Identify the organic functional groups and reaction type for the following reaction if only the major product is shown.The reactant is a(n)a. alkyneb. etherc. alkened. alcohole. aromaticThe product is a(n)a. tertiary alcoholb. primary alcoholc. aldehyded. ethere. secondary alcoholThe reaction type is :a. hydrolysisb. hydrationc. reduction (hydrogenation)d. dehydratione. oxidationarrow_forwardWhich of the following alcohols can be oxidized to a carboxylic acid? Name the carboxylic acid produced. Forthose alcohols that cannot be oxidized to a carboxylic acid,name the final product.a. Ethanol c. 1-Propanolb. 2-Propanol d. 3-Pentanolarrow_forwardGive the reagent or chemical test that would differentiate the following pairs of compounds. Provide only the reagents or chemical tests discussed in the module. Write chemical equations for the reactions involved. a. benzene and ethylbenzene b. 1-butyne and 2-butyne C. 2-methylpentane and 2-methyl- 2-pentene d. toluene and 1-methylcyclohexenearrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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