(a)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into
The combination of
(b)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(c)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(d)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(e)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(f)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(g)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.
The combination of
(h)
To determine: The products of the reactions with the given compound.
Interpretation: The products of the reactions with the given compounds are to be stated.
Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols or aldehyde into carboxylic acid through oxidation reaction.
The combination of
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Chapter 11 Solutions
ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
- Below is the structure of terbutaline, used in the management of asthma symptoms. The tert-butyl substituent on the Nitrogen provides .?. selectivity. OH TERBUTALINE HO ÓH Select one: a.Muscarinic b.Nicotinic c.B1-adrenergic d.al-adrenergic e.82-adrenergicarrow_forwardShow how the following compounds can be prepared from benzene: a. benzaldehyde c. 1-bromo-2-phenylethane e. aniline b. styrene d. 2-phenylethanol f. benzoic acidarrow_forwardWhich of the following compounds among the choices below will not produce a precipitate upon reaction with sodium bisulfite? A. Benzaldehyde B. Methanal C. None of the above D. 2-propanone E. 3-hexanone Kindly explain and justify your answer.arrow_forward
- What is the best choice of reagents to achieve the following reaction? A. SOCl2 (1/2 equivalent) B. KOH (pellets) C. K2SO4 D. PhCO2Naarrow_forwardPhosgene (COCl2) was used as a poison gas in World War I. What product would be formed from the reaction of phosgene with each of the following reagents? a. one equivalent of methanol b. excess methanol c. excess propylamine d. excess waterarrow_forwardWrite reactions of 1-iodo-2-methylpropane with the following reagents: a. Mg/ether b. KOH/H20 c. NaOH/CH3OH d. CH3NH3 e. NaNO2arrow_forward
- What product(s) result from nitration of each of the following? a. propylbenzene c. benzaldehyde e. benzenesulfonic acid b. bromobenzene d. benzonitrile f. cyclohexylbenzenearrow_forwardWrite reactions of 1-iodo-2-methylpropane with the following reagents: a. Mg/ether b. KOH/H20 c. NaOH/CH3OHarrow_forwardWrite the equations showing the reactions of propanoic acid with: a. ammoniab. methanal c. thionyl chlorided. methanaminearrow_forward
- From which starting materials can the product formed as a result of the following reaction be synthesized? A. Acetophenone and butanal B. Benzaldehyde and 3-pentanone C. Benzaldehyde and 2-pentanone D. Acetophenone and 2-butanonearrow_forwardWhat are the products of the following reactions? (A trace amount of acid is present in each case.) a. cyclopentanone + ethylamine c. acetophenone + hexylamine b. cyclopentanone + diethylamine d. acetophenone + cyclohexylaminearrow_forwardWrite reaction of iso-propylamine with the following reagents: a. Ethyl Iodide b. NaNO2 + HCl c. CH3COCl d. HBrarrow_forward
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