The major product should be given, if NH 3 shift occurs. Concept introduction: Aromaticity: The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are, The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 1

Question

Chapter 11.8, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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- How could the following changes in reaction conditions affect the rate of the reaction when isopropanol (IPA) reacts with 2-bromo-2-methylpentane? The concentration of the IPA is halved by adding petroleum ether as the solvent. b. The concentration of the bromoalkene is quadrupled. а.

The existence of the NIH shift was established by determining the major product obtained from rearrangement of the following arene oxide, in which a hydrogen has been replaced by a deuterium. a. What would be the major product if the NIH shift occurs? (Hint: A C¬H bond is easier to break than a C¬D bond.)b. What would be the major product if the carbocation forms phenol by losing H+ or D+, rather than by going through the NIH shift?

The existence of the NIH shift was established by determining the major product obtained from rearrangement of the following arene oxide, in which a hydrogen has been replaced by a deuterium. a. What would be the major product if the NIH shift occurs? b. What would be the major product if the carbocation forms phenol by losing H+ or D+, rather than by going through the NIH shift?

Answer 2

Question

Chapter 11.8, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 3

Question

Chapter 11.8, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 4

Question

Chapter 11.8, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

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Answer 5

Chapter 11.8, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 6

Chapter 11.8, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 7

Chapter 11.8, Problem 32P

(a)

Interpretation Introduction

Interpretation:

The major product should be given, if NH3 shift occurs.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product should be given, if the carbocation forms phenol by losing H+or D+ rather than by going through the NIH shift.

Concept introduction:

Aromaticity:

The aromatic compounds are type of organic compounds, which has a special property’s in the reactivity and structure, they are,

The organic molecule must planar, cyclic and conjugate and satisfy the 4n+2 electrons is called aromatic compound. Aromatic molecules are very stable, and do not break apart easily to react with other substances.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 11.1 - Prob. 2P Ch. 11.1 - Prob. 5P Ch. 11.2 - Prob. 7P Ch. 11.3 - Prob. 9P Ch. 11.3 - Show how 1-propanol can be converted into the...Ch. 11.4 - Which of the following alcohols dehydrates the...Ch. 11.4 - Prob. 12P Ch. 11.4 - Prob. 13P Ch. 11.4 - Propose a mechanism for each of the following...

Solution Summary: The author explains that aromatic compounds are type of organic compounds, which has a special property's in the reactivity and structure.

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