Exploring Chemical Analysis
Exploring Chemical Analysis
5th Edition
ISBN: 9781429275033
Author: Daniel C. Harris
Publisher: Macmillan Higher Education
Question
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Chapter 12, Problem 12.15P
Interpretation Introduction

Interpretation:

Value of activity coefficient and pH in presence of 0.010 M HCl and 0.040 M KClO4 has to be calculated.

Concept Introduction:

Extended Debye Huckel law quantifies activity coefficient in terms of ionic strength and hydrated size as follows:

  logγ=0.51z2μ1+(αμ/305)

Here

z denotes charge.

μ denotes ionic strength.

γ denotes activity coefficient.

α denotes ionic size.

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