Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 12, Problem 12.CCP
Interpretation Introduction
Interpretation:
The reaction between a small crystal of sodium acetate with a
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Combinations of iron(II), H2O, Cl-, and NH4+ can result in the formation of a series of 7 coordination compounds, one of which is [Fe(OH2)6]Cl2.
a. Write the modern formulas for the other 6 members of this series.
b. How many chlorides would be precipitated from [Fe(OH2)6]Cl2 upon the reaction with AgNO3?
Crystals of hydrated chromium(III) chloride are green, have an empirical formula of CrCl3 . 6 H2O, and are highly soluble, Write the complex ion that exists in this compound.
Silver and ammonia may react to form Ag(NH₃)₂⁺ complex (Kf = 1.66 x 107). A 500 mL of 0.10 mol Ag⁺ and 500 mL of 0.70 mol NH₃ are mixed together.a. Write the complexation reaction.b. Write the formation constant expression.c. What is the concentration of the complex at equilibrium?d. What is the concentration of the metal at equilibrium?
Chapter 12 Solutions
Chemistry: The Molecular Science
Ch. 12.1 - The introduction to this chapter states that at a...Ch. 12.1 - Prob. 12.2CECh. 12.2 - After a mixture of cis-2-butene and trans-2-butene...Ch. 12.2 - Prob. 12.1PSPCh. 12.2 - Prob. 12.4ECh. 12.2 - When carbon dioxide dissolves in water it reacts...Ch. 12.2 - For each of these reactions, calculate KP from Kc....Ch. 12.3 - Prob. 12.3PSPCh. 12.4 - Suppose that solid AgCl and AgI are placed in 1.0...Ch. 12.4 - Prob. 12.6CE
Ch. 12.5 - For the equilibrium 2 SO2(g) + O2(g) 2 SO3(g) Kc...Ch. 12.5 - Prob. 12.7CECh. 12.5 - Prob. 12.6PSPCh. 12.5 - Prob. 12.7PSPCh. 12.6 - Prob. 12.8CECh. 12.6 - Prob. 12.9ECh. 12.6 - Prob. 12.10CECh. 12.6 - Prob. 12.8PSPCh. 12.7 - For the ammonia synthesis reaction
⇌
Does the...Ch. 12.8 - Prob. 12.13CECh. 12 - Prob. 1QRTCh. 12 - Prob. 2QRTCh. 12 - Prob. 3QRTCh. 12 - Decomposition of ammonium dichromate is shown in...Ch. 12 - For the equilibrium reaction in Question 4, write...Ch. 12 - Indicate whether each statement below is true or...Ch. 12 - Prob. 7QRTCh. 12 - Prob. 8QRTCh. 12 - Prob. 9QRTCh. 12 - Prob. 10QRTCh. 12 - The atmosphere consists of about 80% N2 and 20%...Ch. 12 - Prob. 12QRTCh. 12 - Prob. 13QRTCh. 12 - Prob. 14QRTCh. 12 - Prob. 15QRTCh. 12 - Prob. 16QRTCh. 12 - Prob. 17QRTCh. 12 - Prob. 18QRTCh. 12 - Prob. 19QRTCh. 12 - Prob. 20QRTCh. 12 - Prob. 21QRTCh. 12 - Prob. 22QRTCh. 12 - Prob. 23QRTCh. 12 - Prob. 24QRTCh. 12 - Prob. 25QRTCh. 12 - Prob. 26QRTCh. 12 - Prob. 27QRTCh. 12 - Prob. 28QRTCh. 12 - Prob. 29QRTCh. 12 - Prob. 30QRTCh. 12 - Given these data at a certain temperature,...Ch. 12 - The vapor pressure of water at 80. C is 0.467 atm....Ch. 12 - Prob. 33QRTCh. 12 - Prob. 34QRTCh. 12 - Prob. 35QRTCh. 12 - Prob. 36QRTCh. 12 - Carbon dioxide reacts with carbon to give carbon...Ch. 12 - Prob. 38QRTCh. 12 - Prob. 39QRTCh. 12 - Prob. 40QRTCh. 12 - Nitrosyl chloride, NOC1, decomposes to NO and Cl2...Ch. 12 - Suppose 0.086 mol Br2 is placed in a 1.26-L flask....Ch. 12 - Prob. 43QRTCh. 12 - Prob. 44QRTCh. 12 - Prob. 45QRTCh. 12 - Using the data of Table 12.1, predict which of...Ch. 12 - Prob. 47QRTCh. 12 - The equilibrium constants for dissolving silver...Ch. 12 - Prob. 49QRTCh. 12 - Prob. 50QRTCh. 12 - At room temperature, the equilibrium constant Kc...Ch. 12 - Prob. 52QRTCh. 12 - Consider the equilibrium N2(g)+O2(g)2NO(g) At 2300...Ch. 12 - The equilibrium constant, Kc, for the reaction...Ch. 12 - Prob. 55QRTCh. 12 - Prob. 56QRTCh. 12 - Prob. 57QRTCh. 12 - At 503 K the equilibrium constant Kc for the...Ch. 12 - Prob. 59QRTCh. 12 - Prob. 60QRTCh. 12 - Prob. 61QRTCh. 12 - Prob. 62QRTCh. 12 - Prob. 63QRTCh. 12 - Prob. 64QRTCh. 12 - Prob. 65QRTCh. 12 - Prob. 66QRTCh. 12 - Prob. 67QRTCh. 12 - Hydrogen, bromine, and HBr in the gas phase are in...Ch. 12 - Prob. 69QRTCh. 12 - Prob. 70QRTCh. 12 - Prob. 71QRTCh. 12 - Prob. 72QRTCh. 12 - Prob. 73QRTCh. 12 - Prob. 74QRTCh. 12 - Consider the system
4 NH3(g) + 3 O2(g) ⇌ 2 N2(g) +...Ch. 12 - Prob. 76QRTCh. 12 - Predict whether the equilibrium for the...Ch. 12 - Prob. 78QRTCh. 12 - Prob. 79QRTCh. 12 - Prob. 80QRTCh. 12 - Prob. 81QRTCh. 12 - Prob. 82QRTCh. 12 - Prob. 83QRTCh. 12 - Prob. 84QRTCh. 12 - Prob. 85QRTCh. 12 - Prob. 86QRTCh. 12 - Prob. 87QRTCh. 12 - Consider the decomposition of ammonium hydrogen...Ch. 12 - Prob. 89QRTCh. 12 - Prob. 90QRTCh. 12 - Prob. 91QRTCh. 12 - Prob. 92QRTCh. 12 - Prob. 93QRTCh. 12 - Prob. 94QRTCh. 12 - Prob. 95QRTCh. 12 - Prob. 96QRTCh. 12 - Prob. 97QRTCh. 12 - Prob. 98QRTCh. 12 - Prob. 99QRTCh. 12 - Prob. 100QRTCh. 12 - Two molecules of A react to form one molecule of...Ch. 12 - Prob. 102QRTCh. 12 - In Table 12.1 (←Sec. 12-3a) the equilibrium...Ch. 12 - Prob. 104QRTCh. 12 - Prob. 105QRTCh. 12 - Prob. 106QRTCh. 12 - Prob. 107QRTCh. 12 - Which of the diagrams for Questions 107 and 108...Ch. 12 - Draw a nanoscale (particulate) level diagram for...Ch. 12 -
The diagram represents an equilibrium mixture for...Ch. 12 - The equilibrium constant, Kc, is 1.05 at 350 K for...Ch. 12 - For the reaction in Question 111, which diagram...Ch. 12 - Prob. 113QRTCh. 12 - Prob. 114QRTCh. 12 - Prob. 115QRTCh. 12 - For the equilibrium...Ch. 12 - Prob. 117QRTCh. 12 - Prob. 119QRTCh. 12 - Prob. 120QRTCh. 12 - When a mixture of hydrogen and bromine is...Ch. 12 - Prob. 122QRTCh. 12 - Prob. 123QRTCh. 12 - Prob. 124QRTCh. 12 - Prob. 125QRTCh. 12 - Prob. 12.ACPCh. 12 - Prob. 12.BCPCh. 12 - Prob. 12.CCPCh. 12 - Prob. 12.DCPCh. 12 - Prob. 12.ECPCh. 12 - Prob. 12.FCP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Predict whether nickel(II) hydroxide, Ni(OH)2, will precipitate from a solution that is 0.0020 M NiSO4, 0.010 M NaOH, and 0.10 M NH3. Note that nickel(II) ion forms the Ni(NH3)62+ complex ion.arrow_forwardA Boric acid and glycerin form a complex B(OH)3(aq) + glycerin(aq) B(OH)3 glycerin(aq) with an equilibrium constant of 0.90. If the concentration of boric acid is 0.10 M, how much glycerin should be added, per liter, so that 60.% of the boric acid is in the form of the complex?arrow_forwardA certain coordination compound has the simplest formula PtN2H6Cl2. It has a molar mass of about 600 g/mol and contains both a complex cation and a complex anion. What is its structure?arrow_forward
- Use the formation constant of [Au(CN)2] in Appendix K to determine the equilibrium concentration of Au+(aq) in a solution that is 0.0071 M CN and 1.1 104 M [Au(CN)2]. Is it reasonable to conclude that 100% of the gold in solution is present as the [Au(CN)2] complex ion? Explain.arrow_forwardSilver and ammonia may react to form Ag(NH₃)₂⁺ complex (Kf = 1.66 x 107). A 500 mL of 0.30mol Ag⁺ and 500 mL of 0.70 mol NH₃ are mixed together.a. Write the complexation reaction.b. Write the formation constant expression.c. What is the concentration of the complex at equilibrium?d. What is the concentration of the metal at equilibrium?arrow_forwardSilver and ammonia may react to form Ag(NH₃)₂⁺ complex (Kf = 1.66 x 107). A 500 mL of 10 mol Ag⁺ and 500 mL of 0.70 mol NH₃ are mixed together. Write the complexation reaction. Write the formation constant expression. What is the concentration of the complex at equilibrium? What is the concentration of the metal at equilibrium?arrow_forward
- In photography, unexposed silver bromide was removed from film by soaking the film in a solution of sodium thiosulfate, Na2S2O3. Silver ion, Ag+, forms a soluble complex with the thiosulfate ion, S2O3-2, that has a formula of Ag(S2O3)2-3, and the formation of the complex causes the AgBr in the film to dissolve. The formation of the complex has a Kf of 2.0 x 10^13 while the Ksp of AgBr is 5.0 x 10^-13. How many grams of AgBr will dissolve in 125 mL of 1.20 M Na2S2O3 solution?arrow_forwardFormation of soluble silver-ammonium complex, in an AgCl solution, occurs on a 3-step process: Based on the chemical equation provided, what do you think is equivalent to K2? a. [Ag(NH3)2+] / {[Ag(NH3)+][NH3]} b. [Ag(NH3)2+] / {[Ag+][NH3+]2} c. [Ag+] [Cl-] d.[AgNH3] / {[Ag+][NH3]}arrow_forwardZinc(II) readily forms the complex ion [Zn(OH)4]2+. Explain how this fact can be used to distinguish a solution of ZnCl2 from MgCl2.arrow_forward
- Silver and ammonia may react to form Ag(NH3)2+ complex (Kf = 1.66 x 107). A 500 mL of 0.20mol Ag+ and 500 mL of 0.80 mol NH3 are mixed together.a. Write the complexation reaction.b. Write the formation constant expression.c. What is the concentration of the complex at equilibrium?d. What is the concentration of the metal at equilibrium?arrow_forwardWhen species combine to produce a coordination complex, the equilibrium constant for the reaction is called is the formation constant, Kf.For example, the iron(II) ion, Fe2+, can combine with the cyanide ion, CN−, to form the complex [Fe(CN)6]4− according to the equation Fe2+(aq)+6CN−(aq)⇌[Fe(CN)6]4−(aq) where Kf=4.21×1045.This reaction is what makes cyanide so toxic to human beings and other animals. The cyanide ion binds to the iron that red blood cells use to carry oxygen around the body, thus interfering with the blood's ability to deliver oxygen to the tissues. It is this toxicity that has made the use of cyanide in gold mining controversial. Most states now ban the use of cyanide in leaching gold out of low-grade ore. The average human body contains 6.30 L of blood with a Fe2+ concentration of 2.50×10−5 M . If a person ingests 9.00 mL of 12.0 mM NaCN , what percentage of iron(II) in the blood would be sequestered by the cyanide ion?arrow_forward
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