ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter 12, Problem 26P
Provide the reagents needed to accomplish transformations (a)-(g). More than one step may be necessary.
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Give an IUPAC and common name for each of the following naturally occurring carboxylic acids: (a) CH3CH(OH)CO2H (lactic acid); (b) HOCH2CH2C(OH)(CH3)CH2CO2H (mevalonic acid).
5
AM
7.12. Draw the structural formula of the enol formed in each alkyne hydration reaction; then draw the
structural formula of the carbonyl compound with which each enol is in equilibrium.
(a) CH, (CH₂), C=CH + H₂O
(b) CH, (CH₂),C=CH
HgSO4
H₂SO4
1. (sia), BH
2. NaOH/H₂O₂
(an enol) →
→(an enol) →
4G. 4G
7:41 PM
27
PROBLEM SET – CARBOXYLIC ACIDS
1. Give IUPAC names for the following carboxylic acids:
(a)
(b)
Br
(c)
CH;CHCH,ČOH
CH;CHCH,CH,ČOH
CH3CH-CHCH,CH,CH3
(d)
H
H
(e)
H
C%3C
HO,C
H3C
CH2CH,COH
2. Draw structures corresponding to the following names:
(a) 2.3-Dimethylhexanoic acid
(b) 4-Methylpentanoic acid
Chapter 12 Solutions
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
Ch. 12 - Prob. 1PPCh. 12 - Prob. 2PPCh. 12 - Prob. 3PPCh. 12 - PRACTICE PROBLEM 12.4 Predict the products of the...Ch. 12 - Prob. 5PPCh. 12 - Prob. 6PPCh. 12 - Practice Problem 12.7
Provide retrosynthetic...Ch. 12 - Prob. 8PPCh. 12 - What products would you expect from the reaction...Ch. 12 - What products would you expect from the reaction...
Ch. 12 - What product (or products) would be formed from...Ch. 12 - Prob. 12PCh. 12 - 12.13 Write reaction conditions and the product...Ch. 12 - Prob. 14PCh. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the major organic product from each of the...Ch. 12 - Synthesize each of the following compounds from...Ch. 12 - Prob. 20PCh. 12 - 21. Write a mechanism for the following reaction....Ch. 12 - Prob. 22PCh. 12 - 23. What organic products A-H would you expect...Ch. 12 - Prob. 24PCh. 12 - Show how 1-pentanol could be transformed into each...Ch. 12 - Provide the reagents needed to accomplish...Ch. 12 - Prob. 27PCh. 12 - For each of the following alcohols, write a...Ch. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Predict the major organic product from each of the...Ch. 12 - 34. Synthesize the following compound using...Ch. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - 37. Explain how and IR spectroscopy could be used...Ch. 12 - 38. An unknown X shows a broad absorption band in...Ch. 12 - Prob. 39PCh. 12 - The problem below is directed toward devising a...
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