MASTERING CHEMISTRYPLUS F/CHEM.-ACCESS
12th Edition
ISBN: 9781269874601
Author: Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 12.2, Problem 12.10PP
Classify each of the following alcohols as primary (1°), secondary (2°), or tertiary (3°):
a.
b.
c.
d.
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Molecule
Type
Boiling point (°C)
CH3CH2CH3
Alkane
-42
CH3CHO
Aldehyde
+21
CH3CH2OH
Alcohol
+78
i. Why is the boiling point of the aldehyde greater than that of the alkane?ii. Why is the boiling point of alcohol the highest?iii. Explain why the solubility of aldehydes and alcohols falls as the molecules get bigger.
1. Why 70% alcohol is used as disinfectant?
2. Why pure concentrated alcohol is not 100%?
3. What are the symptoms of alcohol intoxication?
ALCOHOLS
1. WHY IS ETHANOL MORE SOLUBLE IN WATER THAN 1-HEXANOL?
2. WHAT IS DENATURED ALCOHOL? AND WHY IS ALCOHOL DENATURED?
ETHER
1. WHY DOES DIETHYL ETHER HAVE MUCH LOWER BOILING POINT THAN 1-BUTANOL?
Chapter 12 Solutions
MASTERING CHEMISTRYPLUS F/CHEM.-ACCESS
Ch. 12.1 - Give the IUPAC name for each of the following: a....Ch. 12.1 - Give the IUPAC name for each of the following: a....Ch. 12.1 - Prob. 12.3PPCh. 12.1 - Draw the condensed structural formula, or...Ch. 12.1 - Give the common name for each of the following: a....Ch. 12.1 - Prob. 12.6PPCh. 12.1 - Draw the condensed structural formula, or...Ch. 12.1 - Draw the condensed structural formula, or...Ch. 12.2 - Classify each of the following alcohols as primary...Ch. 12.2 - Classify each of the following alcohols as primary...
Ch. 12.2 - Prob. 12.11PPCh. 12.2 - Prob. 12.12PPCh. 12.2 - Give an explanation for each of the following...Ch. 12.2 - Give an explanation for each of the following...Ch. 12.3 - Identify each of the following compounds as an...Ch. 12.3 - Identify each of the following compounds as an...Ch. 12.3 - Give the common name for each of the following: a....Ch. 12.3 - Give the common name for each of the following: a....Ch. 12.3 - Give the IUPAC name for each of the following: a....Ch. 12.3 - Give the IUPAC name for each of the following: a....Ch. 12.3 - Draw the condensed structural formula for each of...Ch. 12.3 - Draw the condensed structural formula for each of...Ch. 12.3 - Which compound in each of the following pairs...Ch. 12.3 - Which compound in each of the following pairs...Ch. 12.4 - Write the balanced chemical equation for the...Ch. 12.4 - Write the balanced chemical equation for the...Ch. 12.4 - Prob. 12.27PPCh. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural formulas for the...Ch. 12.4 - Draw the condensed structural formulas for the...Ch. 12.4 - Prob. 12.33PPCh. 12.4 - Prob. 12.34PPCh. 12.4 - Oxybenzone is an effective sunscreen whose...Ch. 12.4 - Avobenzone is a common ingredient in sunscreen....Ch. 12 - Prob. 12.37UTCCh. 12 - The compound frambinone has the taste of...Ch. 12 - A compound called resveratrol is an antioxidant,...Ch. 12 - A compound called cinnamaldehyde is found in...Ch. 12 - Prob. 12.41UTCCh. 12 - Prob. 12.42UTCCh. 12 - Prob. 12.43APPCh. 12 - Classify each of the following alcohols as primary...Ch. 12 - Give the IUPAC name for each of the following...Ch. 12 - Give the IUPAC name for each of the following...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Which compound in each pair would be more soluble...Ch. 12 - Which compound in each pair would be more soluble...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Give the IUPAC name for each of the following:...Ch. 12 - Give the IUPAC name for each of the following:...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Which of the following aldehydes or ketones are...Ch. 12 - Which of the following aldehydes or ketones are...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Prob. 12.63CPCh. 12 - Draw the condensed structural formulas and give...Ch. 12 - A compound with the formula C4H8O is synthesized...Ch. 12 - A compound with the formula C5H10O oxidizes to...Ch. 12 - Compound A is a primary alcohol whose formula is...Ch. 12 - Compound X is a secondary alcohol whose formula is...Ch. 12 - Prob. 21CICh. 12 - Prob. 22CICh. 12 - Prob. 23CICh. 12 - Prob. 24CICh. 12 - Prob. 25CICh. 12 - lonone is a compound that gives violets their...
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- Label each of the following structures as a hemiacetal, hemiketal, acetal, ketal, or none of these: a. c. b.arrow_forwardDraw the condensed formulas for each of the following compounds: (a) dipropyl ether. (b) 2, 2-dimethyl-3-hexanol. (c) 2-ethoxybutanearrow_forwardExplain the reasons for the following observed properties: (a) Carboxylic acids have higher boiling point than alcohols of similar molecular mass (b) Acetone is soluble in waterarrow_forward
- Cyclohexane is expected to be most soluble in: HCl water None of the above pentane HIarrow_forwardLabel each ether and alcohol in brevenal, a marine natural product. Classify each alcohol as 1°, 2°, or 3°.arrow_forwardn-Butyl methyl ether is an isomer of MTBE and has a boiling point of 70 oC. Explain why the boiling point is significantly different compared to MTBE.arrow_forward
- Label each of the following structures as a cyclic hemiacetal, hemiketal, acetal, ketal, or none of these: a. b. c.arrow_forward1. which one is water-soluble based on their structure? pls explain whya. vitamin A b. vitamin B3 c. vitamin E d. both b and C2. arrange from most soluble to least soluble in watera. methanol b.1-butanol c. ethylene glycol d. 2-octanolarrow_forwardi. Why is the boiling point of the aldehyde greater than that of the alkane? ii. Why is the boiling point of alcohol the highest? iii. Explain why the solubility of aldehydes and alcohols falls as the molecules get bigger.arrow_forward
- Why CH3CH2NHCH3 has higher boiling point tha (CH3)3N even they have the same molecular weightarrow_forwardTHC is the active component in marijuana, and ethanol is the alcohol in alcoholic beverages. Explain why drug screenings are able to detect the presence of THC but not ethanol weeks after these substances have been introduced into the body.arrow_forwardALCOHOLS 1. WHY IS METHANOL MORE TOXIC THAN ETHANOL? 2. FROM WHAT ALKENE IS ETHANOL MADE? DRAW ITS CONDENSED STRUCTURAL FORMULA 3. HOW DOES RUBBING ALCOHOL A FEVERISH PATIENT?arrow_forward
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