Organic Chemistry As a Second Language: First Semester Topics
Organic Chemistry As a Second Language: First Semester Topics
4th Edition
ISBN: 9781119110668
Author: David R. Klein
Publisher: WILEY
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Chapter 12.5, Problem 12.22P
Interpretation Introduction

Interpretation:

The expected product has to be drawn for the given reaction.

Concept Introduction:

Alkynes are the compounds that contain a triple bond between two carbon atoms.  The carbon atom present in the triple bond is sp hybridised.  Due to this, the geometry of alkyne will be linear.  Terminal alkyne are the one which has a proton attached to the triple bond and internal alkyne are the one in which there are no protons attached to the triple bond.

Organic Chemistry As a Second Language: First Semester Topics, Chapter 12.5, Problem 12.22P , additional homework tip  1

Hydration of Alkynes:

Alkynes undergo hydration reaction in presence of acid and mercuric sulfate as catalyst to form an enol as the initial product.  The formed enol gets converted fast into keto due to keto-enol tautomerism.  Ketone and enol are constitutional isomers.  If the alkyne under consideration is a terminal alkyne, then methyl ketone will be the product that is obtained.  The general scheme for hydration of alkyne can be given as shown below,

Organic Chemistry As a Second Language: First Semester Topics, Chapter 12.5, Problem 12.22P , additional homework tip  2

Hydration of alkynes through the method said above is a Markovnikov addition.

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