(a)
Interpretation:
Structure has to be drawn for primary amide that has molecular formula of
Concept Introduction:
Amides contain a nitrogen atom that is bonded to carbonyl group. The nitrogen atom that is bonded to the carbonyl group may be bonded to alkyl groups or hydrogen atoms. Depending on the number of carbon atoms that is attached to the nitrogen atom, the amide is classified as primary, secondary, and tertiary.
Primary amide is the one that contains only one
(b)
Interpretation:
Structure has to be drawn for secondary amide that has molecular formula of
Concept Introduction:
Refer part (a).
(c)
Interpretation:
Structure has to be drawn for tertiary amide that has molecular formula of
Concept Introduction:
Refer part (a).
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Chapter 13 Solutions
Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
- Because amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forwardExplain why CH3 CH2 CH2NH2 is a Brønsted base. Its water solutions are basic. All substances containing nitrogen atoms are Brønsted bases. This amine is a proton donor. This amine can ассеpt a proton from a proton donor.arrow_forward(a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.arrow_forward
- Give the IUPAC or common name of the amine formed in the reaction below between an amine salt and a base? (CH3)2NH2+Cl−+NaOH→ ?+NaCl+H2O(CH3)2NH2+Cl−+NaOH→ ?+NaCl+H2Oarrow_forwardThe following amines have the same molecular formula (C5H13N), but their boiling points are significantly different. Explain why. H `NH2 2-Methylbutan-1-amine Boiling point = 97 °C N-Methylbutan-2-amine Boiling point = 84 °C N-Ethyl-N-methylethan-1-amine Boiling point = 65 °Carrow_forward(a) Identify the functional groups in salinosporamide A, an anticanceragent isolated from marine sediment. (b) Classify each alcohol, alkylhalide, amide, and amine as 1°, 2°, or 3°.arrow_forward
- Which of the following is a tertiary amine? C) N-H CH₂ N-CH₂ H₂C b) NH₂ CH₂ CH₂ H₂CH N CH, d) H₂c-c CH, C-CH₂ CHarrow_forwardWhat products are formed when benzoic acid (C 6H 5COOH) is treated with each base: (a) NaOH; (b) Na 2CO 3; (c) NaHCO 3?arrow_forwardWhich compound makes the strongest amine base? `N CH3 -N- 1 2 3 4 Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a Compound 1 b Compound 2 Compound 3 d Compound 4arrow_forward
- Draw the structure of M-P-V-G, and indicate its amide bonds.arrow_forward16-13 Classify each amino group as primary, secondary, or tertiary and as aliphatic or aromatic. Serotonin (a neurotransmitter) Diphenhydramine (the hydrochloride salt is the antihistamine Benadryl) Lysine (an amino acid)arrow_forwardUsing the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.arrow_forward
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