Without using the great orthogonality theorem, reduce the given irreducible representation in
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Chapter 13 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
- Show that any two of the irreducible representations of the following point groups are orthogonal to each other. a C2 b C2v c D2h d Oh e Tdarrow_forwardWhy is it unnecessary to consider whether an irreducible representation from C4h is orthogonal to an irreducible representation of D6h?arrow_forwardExplain why a molecule with a center of inversion cannot have a dipole moment.arrow_forward
- Construct the Hckel determinants for cyclobutadiene and cyclopentadiene. In what ways are they alike? In what ways are they different?arrow_forwardIm confused with this C3 C P C32 Point Group: σh S3arrow_forwardWhat is the reducible representation for N205? Determine the reducible representation (T) that describes all the degrees of freedom .arrow_forward
- - Determine the irreducible representations with reasons in the following character table. C I R R, R xy.arrow_forwardB) Identify all the elements of symmetry of IrCl(CO) [P(C6H5)3]2 and the point group assignment. PPH3 B CI- C=O Ph3Parrow_forwardA scrambled character table for a polyhedral point group is shown here, though missing a couple of its characters. All symmetry elements and irreducible representations are included in this table. 6 S4 1 1 -1 -1 [₁ [₂ Гз T4 [5 What is the order of this point group? How many classes does this point group have? E 1 2 1 3 ? 8 C3 1 3 C₂ 1 -1 ? 1 0 −1 (report a positive integer) ? -1 2 6 Od 1 -1 -1 ? 0 (report a positive integer)arrow_forward
- D3h Г E 6 Reduce the following representation into its irreducible components 2C3 2S3 30v 3 1 4 3C₂ Oh 2 4arrow_forwardBelow is a part of a character table of a certain point group. 2C4 C2 20 v 20 d E A1 1 1 1 1 1 1 -1 -1 A2 1 -1 1 1 -1 B1 -1 1 -1 1 B2 -2 E The symmetry representation label B2 has a basis function correspoding to what d atomic orbital? (z-axis is the principal axis) d22 O dyz O dy2-y2 O dyy O dyz 1.arrow_forwardThe molecule of interest PtCl4^2-. Find the irreducible representation(s) of the pz orbitals, using the pz orbitals of Cl. Also, use the projection operator method and show what one irreducible representation looks like. What orbitals if any match up with the orbital on Pt (from a pure symmetry approach)arrow_forward
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning