The major product for the given reaction should be identified. Concept introduction: Bromination: Alcohols brominated by using Pbr 3 which provides corresponding brominated products. Chlorination: Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products. Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products. E 1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination. Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde . Alcohols undergoing oxidation by using oxidizing agent like Na 2 Cr 2 O 7 (chromic acid) which provides carboxylic acid. Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base. Alcohols treated with any metals or base which provides alkoxide.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 35PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(l)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 35PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(l)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 35PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(l)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 13, Problem 35PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(l)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

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Check out a sample textbook solution

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Answer 5

Chapter 13, Problem 35PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

(l)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 6

Chapter 13, Problem 35PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 7

Chapter 13, Problem 35PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 20

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 21

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 22

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 23

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 24

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 25

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 26

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 27

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 28

(l)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 29

(l)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr₃which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

E₁ Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na₂Cr₂O₇ (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

Answer 30

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Answer 31

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Answer 32

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Answer 33

Ch. 13.1 - Prob. 1LTS Ch. 13.1 - Prob. 1PTS Ch. 13.1 - Prob. 2ATS Ch. 13.1 - Prob. 3CC Ch. 13.2 - Prob. 4CC Ch. 13.2 - Prob. 2LTS Ch. 13.2 - Prob. 5PTS Ch. 13.2 - Prob. 6ATS Ch. 13.3 - Prob. 7CC Ch. 13.3 - Prob. 8CC

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Chapter 13 Solutions