Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 13, Problem 49PP

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept introduction:

Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

 (b)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept introduction:

Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

 (c)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept introduction:

Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

(d)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept introduction:

Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

(e)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept introduction:

Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

 (f)

Interpretation Introduction

Interpretation:

The product for the given reaction should be identified.

Concept introduction:

Ozonolysis: The unsaturated bonds like alkenes, alkynes, and azo compounds are cleaved with ozone are called ozonolysis. The alkenes and alkynes in which the multiple carbon–carbon bonds have been changed by a carbonyl group

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

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Chapter 13 Solutions

Organic Chemistry

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