CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Chapter 13, Problem 38P
Explain why radical bromination of p-xylene forms
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b) Explain why m-xylene undergoes nitration 100 times faster than p-xylene.
The Friedel-Crafts Alkylation of p-xylene n-propyl bromide can result in an isopropyl as well as n-propyl substitution.
A) Write the chemical equation involved in this reaction.
B) Which will be the major and minor product? What do you expect will be the ratio of n-propyl to isopropyl substitution for p-xylene?
Draw the structure of the minor product formed in the reaction of 2-methylbut-1-ene with
concentrated sulfuric acid
Explain why thid is the major product?
Structure of minor product?
Explanation?
Chapter 13 Solutions
CNCT ORG CHEM 6 2020
Ch. 13.1 - Prob. 1PCh. 13.1 - Prob. 2PCh. 13.2 - Prob. 3PCh. 13.3 - Prob. 4PCh. 13.3 - Prob. 5PCh. 13.4 - Prob. 7PCh. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9PCh. 13.6 - Prob. 10PCh. 13.7 - Prob. 11P
Ch. 13.7 - Prob. 12PCh. 13.8 - Prob. 13PCh. 13.8 - Prob. 14PCh. 13 - Prob. 27PCh. 13 - Prob. 28PCh. 13 - Prob. 34PCh. 13 - 15.37 What alkane is needed to make each alkyl...Ch. 13 - 15.38 Which alkyl halides can be prepared in good...Ch. 13 - Prob. 37PCh. 13 - 15.40 Explain why radical bromination of p-xylene...Ch. 13 - a. What product(s) (excluding stereoisomers) are...Ch. 13 - Prob. 40PCh. 13 - 15.43 Draw the products formed when each alkene is...Ch. 13 - 15.44 Draw all constitutional isomers formed when...Ch. 13 - 15.45 Draw the organic products formed in each...Ch. 13 - Prob. 45PCh. 13 - 15.47 Treatment of a hydrocarbon A (molecular...Ch. 13 - 15.48 Draw the products formed in each reaction...Ch. 13 - 15.53 Consider the following bromination: .
a....Ch. 13 - 15.54 Draw a stepwise mechanism for the following...Ch. 13 - Prob. 57PCh. 13 - 15.57 Devise a synthesis of each compound from...Ch. 13 - Prob. 59PCh. 13 - Prob. 60PCh. 13 - 15.60 Devise a synthesis of each compound using ...Ch. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - 15.63 As described in Section 9.16, the...Ch. 13 - 15.64 Ethers are oxidized with to form...
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- Draw all monochlorination products obtained from the free radical chlorination of 2,3,5-trimethylhexane (include all stereoisomers)arrow_forwardExplain Electrostatic potential maps of four halomethanes (CH3X)arrow_forwardRadical bromination of propene using NBS gives 3-bromo-1-propene. Draw the allylic radical intermediate formed during this reaction, showing both resonance structures.arrow_forward
- Two products are possible when pent-2-ene is treated with HBr. Write the structures of the possible products, and explain why they are made in about equal amounts.arrow_forwardDraw the major organic product formed by reaction of 2-hexyne with the following reagent: H₂O in H₂SO4 / HgSO4. • Consider E/Z stereochemistry of alkenes. • In cases where there is more than one answer, just draw one. • If no reaction occurs, draw the organic starting material.arrow_forward1. b) Show the MECHANISM for the POLAR addition of molecular chlorine to cyclopentane. c) The reaction of toluene and ethylbenzene was through the alkyl groups, -CH 3 and -CH 2 CH 3, respectively. Why didn’t xylene, which has TWO methyl groups, react with bromine in the time allotted?arrow_forward
- Draw the product formed when each triene undergoes electrocyclic reaction under [1] thermal conditions; [2] photochemical conditions.arrow_forwardWhich alkene reacts with a red-brown solution of bromine to form 1,2-dibromo-1-ethylcyclohexane.arrow_forwardExplain the relative reaction rates of addition to alkenes of HCl, HBr, and HI.arrow_forward
- 10) For the reaction between isopropyl 1-propyl (or 'n-propyl') ether and HBr, which type of reaction best matches the expected products? A) Acid-catalyzed dehydration B) Nucleophilic substitution reaction C) Ether cleavage reaction D) Nucleophilic addition-elimination reactionarrow_forwardExplain why m-xylene undergoes nitration 100 times faster than p-xylene.arrow_forwardWhich product is formed by the bromination of 2-butene?arrow_forward
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