EBK THERMODYNAMICS: AN ENGINEERING APPR
8th Edition
ISBN: 8220100257056
Author: CENGEL
Publisher: YUZU
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Chapter 13.3, Problem 100RP
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What is the Δr xn G o (in KJ/mole) for a mole of an ideal gas as pressure changes from 0.1 Pa to 1 x10 5 Pa?
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A cylinder contains oxygen at a pressure of 2.00 atm. The volume is 4.00 L, and the temperature is 300 K. Assume that the oxygen may be treated as an ideal gas. The oxygen is carried through the following processes: (i) Heated at constant pressure from the initial state (state 1) to state 2, which has T = 450 K. (ii) Cooled at constant volume to 250 K (state 3). (iii) Compressed at constant temperature to a volume of 4.00 L (state 4). (iv) Heated at constant volume to 300 K, which takes the system back to state 1. (a) Show these four processes in a pV-diagram, giving the numerical values of p and V in each of the four states. (b) Calculate Q and W for each of the four processes. (c) Calculate the net work done by the oxygen in the complete cycle. (d) What is the efficiency of this device as a heat engine? How does this compare to the efficiency of a Carnot-cycle engine operating between the same minimum and maximum temperatures of 250 K and 450 K?
One mol of a gaseous mixture has the following gravimetric analysis: O2 = 16%, CO2 = 44%, N2 = 40%. The pressure of mixture is 30 psia. Find gas constant of the mixture in BTU/(lb∙°R) and find volumetric analysis for O2 in %.
Chapter 13 Solutions
EBK THERMODYNAMICS: AN ENGINEERING APPR
Ch. 13.3 - Consider a mixture of several gases of identical...Ch. 13.3 - Somebody claims that the mass and mole fractions...Ch. 13.3 - The sum of the mole fractions for an ideal-gas...Ch. 13.3 - Consider a mixture of two gases. Can the apparent...Ch. 13.3 - What is the apparent molar mass for a gas mixture?...Ch. 13.3 - Prob. 6PCh. 13.3 - Consider a mixture of two gases A and B. Show that...Ch. 13.3 - The composition of moist air is given on a molar...Ch. 13.3 - Prob. 9PCh. 13.3 - Prob. 10P
Ch. 13.3 - Prob. 11PCh. 13.3 - Prob. 12PCh. 13.3 - Prob. 13PCh. 13.3 - Is a mixture of ideal gases also an ideal gas?...Ch. 13.3 - Express Daltons law of additive pressures. Does...Ch. 13.3 - Express Amagats law of additive volumes. Does this...Ch. 13.3 - How is the P-v-T behavior of a component in an...Ch. 13.3 - Prob. 18PCh. 13.3 - Prob. 19PCh. 13.3 - Prob. 20PCh. 13.3 - Prob. 21PCh. 13.3 - Consider a rigid tank that contains a mixture of...Ch. 13.3 - Is this statement correct? The volume of an...Ch. 13.3 - Is this statement correct? The temperature of an...Ch. 13.3 - Is this statement correct? The pressure of an...Ch. 13.3 - Prob. 26PCh. 13.3 - Prob. 27PCh. 13.3 - Prob. 28PCh. 13.3 - 13–29 A gas mixture at 350 K and 300 kPa has the...Ch. 13.3 - Prob. 30PCh. 13.3 - Prob. 31PCh. 13.3 - A rigid tank that contains 2 kg of N2 at 25C and...Ch. 13.3 - Prob. 33PCh. 13.3 - Prob. 34PCh. 13.3 - Prob. 35PCh. 13.3 - Prob. 36PCh. 13.3 - A 30 percent (by mass) ethane and 70 percent...Ch. 13.3 - Prob. 38PCh. 13.3 - Prob. 39PCh. 13.3 - Prob. 40PCh. 13.3 - Prob. 41PCh. 13.3 - Prob. 42PCh. 13.3 - Prob. 43PCh. 13.3 - Is the total internal energy of an ideal-gas...Ch. 13.3 - Prob. 45PCh. 13.3 - Prob. 46PCh. 13.3 - 13–47C Is the total internal energy change of an...Ch. 13.3 - Prob. 48PCh. 13.3 - Prob. 49PCh. 13.3 - The volumetric analysis of a mixture of gases is...Ch. 13.3 - Prob. 52PCh. 13.3 - Prob. 53PCh. 13.3 - Prob. 54PCh. 13.3 - Prob. 55PCh. 13.3 - Prob. 56PCh. 13.3 - An insulated tank that contains 1 kg of O2at 15C...Ch. 13.3 - Prob. 59PCh. 13.3 - Prob. 60PCh. 13.3 - Prob. 61PCh. 13.3 - Prob. 62PCh. 13.3 - Prob. 63PCh. 13.3 - Prob. 64PCh. 13.3 - Prob. 66PCh. 13.3 - Prob. 67PCh. 13.3 - Prob. 69PCh. 13.3 - A pistoncylinder device contains 6 kg of H2 and 21...Ch. 13.3 - Prob. 71PCh. 13.3 - Prob. 72PCh. 13.3 - Prob. 73PCh. 13.3 - Prob. 74PCh. 13.3 - Prob. 75PCh. 13.3 - Prob. 76PCh. 13.3 - Prob. 77PCh. 13.3 - Prob. 78PCh. 13.3 - Prob. 80PCh. 13.3 - Prob. 81PCh. 13.3 - Fresh water is obtained from seawater at a rate of...Ch. 13.3 - Prob. 83PCh. 13.3 - Prob. 84RPCh. 13.3 - The products of combustion of a hydrocarbon fuel...Ch. 13.3 - Prob. 89RPCh. 13.3 - Prob. 91RPCh. 13.3 - Prob. 92RPCh. 13.3 - A spring-loaded pistoncylinder device contains a...Ch. 13.3 - Prob. 94RPCh. 13.3 - Reconsider Prob. 1395. Calculate the total work...Ch. 13.3 - A rigid tank contains a mixture of 4 kg of He and...Ch. 13.3 - Prob. 97RPCh. 13.3 - Prob. 100RPCh. 13.3 - An ideal-gas mixture whose apparent molar mass is...Ch. 13.3 - 13–102 An ideal-gas mixture consists of 2 kmol of...Ch. 13.3 - An ideal-gas mixture consists of 2 kmol of N2and 4...Ch. 13.3 - Prob. 104FEPCh. 13.3 - Prob. 105FEPCh. 13.3 - An ideal-gas mixture consists of 3 kg of Ar and 6...Ch. 13.3 - Prob. 107FEPCh. 13.3 - Prob. 108FEPCh. 13.3 - Prob. 109FEPCh. 13.3 - Prob. 110FEP
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- One mol of a gaseous mixture has the following gravimetric analysis: O2 = 16%, CO2 = 44%, N2 = 40%. The pressure of mixture is 30 psia. Find volumetric analysis for O2 in %.arrow_forwardOne mol of a gaseous mixture has the following gravimetric analysis: O2 = 16%, CO2 = 44%, N2 = 40%. The pressure of mixture is 30 psia. Find partial pressure of CO2 in psia.arrow_forwardThe isothermal compressibility, κT, of water at 293 K is 4.96 × 10−5 atm−1. Calculate the pressure that must be applied in order to increase its density by 0.10 per cent.arrow_forward
- A 6-kg block of copper at 300 °C is submerged in 0.08 m3 of water at 0 °C contained in an insulated tank. Estimate the final equilibrium temperature. Conservation of energy requires that the energy lost by the copper block is gained by the water. Units are in Celsius.arrow_forwardAt low pressures, the compressibility factor of a van der Waals gas is given by the equation: Z = PV/RT = 1+(b- a/RT) P/RT Calculate the fugacity of nitrogen gas at 3000 K and 0.05 bar. The van der Waals constants of nitrogen gas are a = 1.408 L^2-bar-mol^2 and b = 0.03913 L-mol^-1. By investigating the fugacity coefficient, what can be said about nitrogen at this temperature and pressure? *final answer in 4 decimalsarrow_forwardCarbon dioxide and oxygen is placed each inside a 1 m^3 tank separated by an isolation valve. Initially, carbon dioxide has the following properties: P=20 kPag & T=25 degrees celsius and that oxygen has the following properties: P=30 kPag & T=75 degrees celsius. If heat is being prevented to escape in the outside surroundings, determine the resulting temperature of the mixture if it is found that after opening the isolation valve, the resulting presure on both tank if 25 kPag.arrow_forward
- One mol of a gaseous mixture has the following gravimetric analysis: O2 = 16%, CO2 = 44%, N2 = 40%. The pressure of mixture is 30 psia. Find gas constant of the mixture in BTU/(lb∙°R).arrow_forwardA tank is filled with 2.5 kg water vapor at 150 bar and 350°C. Determine its volume (m3) using; Compressibility factor, Z from generalized compressibility chart steam table (can you provide the explanation too plz)arrow_forwardExplain the COMPRESSIBILITY FACTOR—A MEASURE OF DEVIATION FROM IDEAL-GAS BEHAVIORarrow_forward
- A piston- cylinder device contains 0.1m ^ 3 of liquid water and 0.9m ^ 3 of water vapor in equilibrium at 800 kPa. Heat is transferred at constant pressure until the temperature reaches 350 degrees * C . i. What is the initial temperature of the water? ii Determine the total mass of the water. iii. Calculate the final volume. iv. Show the process on a P-v diagram with respect to saturation linesarrow_forwardSupposing two liquids of different densities ρ=1750 kg/m3 and ρ=500 kg/m3 were poured together inside a 100L tank, filling it. If the resulting density of the mixture is 750 kg/m3, find (a) the mass and volume of each liquids used, (b) the weight of the mixture if the local acceleration due to gravity is g=9.81 m/s2.arrow_forwardQ4 Show that for a gas obeying van der Walls equation of state, 2a Cp – Cy = R + vTarrow_forward
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