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GENERAL CHEMISTRY-SOLUTIONS MANUAL
- Calcium chloride, CaCl2, has been used to melt ice from roadways. Given that the saturated solution is 32% CaCl2 by mass, estimate the freezing point.arrow_forwardWhat is the freezing point and normal boiling point of a solution made by adding 39 mL of acetone, C3H6O, to 225 mL of water? The densities of acetone and water are 0.790 g/cm3 and 1.00 g/cm3, respectively.arrow_forward(a) If you dissolve 10.0 g (about one heaping teaspoonful) of sugar (sucrose, C12H22O11) in a cup of water (250. g), what are the mole fraction, molality, and weight percent of sugar? (b) Seawater has a sodium ion concentration of 1.08 104 ppm. If the sodium is present in the form of dissolved sodium chloride, what mass of NaCl is in each liter of seawater? Seawater is denser than pure water because of dissolved salts. Its density is 1.05 g/mLarrow_forward
- 6-74 An osmotic semipermeable membrane that allows only water to pass separates two compartments, A and B. Compartment A contains 0.9% NaCI, and compartment B contains 3% glycerol C3H8O3. (a) In which compartment will the level of solution rise? (b) Which compartment (if either) has the higher osmotic pressure?arrow_forwardConsider two solutions, A and B, separated by an osmotic semipermeable membrane that allows only water to pass through, as shown in the diagram in Problem 8-113. Based on each of the following identities for solutions A and B, indicate whether the liquid level in compartment A, with time, will increase, decrease, or not change. a. A = 1.0 M glucose solution and B = 2.0 M glucose solution b. A = 5.0%(m/v) NaCl solution and B = 4.0%(m/v) NaCl solution c. A = 2.0 M Na2SO4 solution and B = 3.0 M KNO3 solution d. A = 2.0 M glucose solution and B = 1.0 M NaCl solutionarrow_forward6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forward
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