Chemistry In Context
Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 14, Problem 14.16YT
Interpretation Introduction

Interpretation:

The functional groups should be assigned from the given IR spectral image.

Concept Introduction:

IR spectroscopy: IR spectrum provides the information regarding the functional groups a compound possesses.  When a molecule is bombarded with radiation of a frequency that exactly matches the frequency of the vibration of one of its bonds, the molecules absorbs energy.

Example:

  • • In the IR spectrum, the signal just above 3000cm1 confirms the presence of  aromatic ring
  • Aromatic compound also produces a series of signals between 1450cm1 and 1650cm-1 in the IR spectrum

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PROCEDURE:A. KEROSENE1. Place 3 drops of kerosene in an evaporating dish, and carefully apply a lightedmatch to the surface of the liquid.Result: _______________________________________________________________________What hydrocarbons are present in kerosene? __________________________________2. To 1 mL of kerosene, add 3 drops of bromine. Result: ____________________________What does this prove? ________________________________________________________3. To 1 mL of kerosene, add 3 drops of dilute potassium permanganate solution.Result: _______________________________________________________________________What does this prove? ________________________________________________________B. GASOLINE (CAUTION! No flame should be lighted in this portion).1. To 3 mL of gasoline, add 3 drops of bromine (CAUTION!). Result: _________________If the solution remains colored, divide it into 2 portions. Place one portion in thedark and the other potion in a bright light. After 10 minutes, compare the…
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