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Chapter 14 Solutions
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
- What is product of the SN1reaction of 4-bromo-3,3-dimethylhexane with methanol (CH3OH) Select one: a. 3,4-dimethyl-3-methoxy-hexane b. 3,3-dimethyl-3-methoxy-hexane c. 4,4-dimethyl-3-methoxy-hexane d. 3,4-dimethyl-3-hexanol e. 3,4-dimethyl-4-methoxy-hexanearrow_forwardThese reagents can produce ketones with alkynes A. BH3, THF, H2O2 B. KMnO4 C. O3 D. H2SO4, H2O, HgSO4arrow_forwardWhich of the provided schemes can be used to synthesize p-chlorophenol p-chlorophenol from benzen e? A. None of the below schemes are correct B. O C. D. SO3 H₂SO4 Cl₂ FeCl 903 H₂SO4 Product Product Product 1. NaOH 2. H₂O* SO 3 H₂SO4 Cl₂ FeCl Product Product Product Cl₂ FeCl H₂/Pd 1. NaOH 2. H₂O* p-Chlorophenol p-Chlorophenol p-Chlorophenolarrow_forward
- The major product form the reaction shown below is.. H3C TSOH (acid) CH2CH3 Select one: a. 2-ethyl-4-methylfuran b. 2-ethyl-tetrahydro-5-methylfuran O c. 2-ethyl-3-methylfuran O d. 2-ethyl-5-methylfuranarrow_forward4. Propose a synthesis of each of the following compounds using the indicated starting material. You may use any organic compounds and any inorganic compounds or solvents of your choice. Do not show any reactive intermediates, mechanisms, or transition states, but be sure to show each isolable compound along your synthetic route. a. b. C. H3 -CH3 steps Ph Ph steps 4 CN steps -CH₂ Ph Ph -OH (racemic)arrow_forwardUpon carrying out a mechanism for the following reaction, state which of the following products would be the major product? A. 3,3-Dimethylbutan-2-ol B. 2,2-Dimethylbutan-4-ol C. 3,3-Dimethylbutan-4-ol D. 4,4-Dimethylbutan-1-ol E. 1'-3,3-Dimethylbutyl alcoholarrow_forward
- 4. Name this ether correctly. CH3CH2CH2CH2-o-CHCH=CHCH3 ČH3 5. Show the best way to make the ether in Prob. #4, using a Williamson Ether Synthesis, starting from an alcohol/phenol.arrow_forward5. Propose a synthesis of each of the following compounds using the indicated starting material. You may use any organic compounds, inorganic compounds, organometallic compounds, or solvents of your choice. Do not show any reactive intermediates, mechanisms, or transition states, but be sure to show each isolable compound along your synthetic route. a. b. C. Ph + PPh3 Cl mylom Ph. CH3 steps steps steps H3C. H3C Ph CH3 CH3 Ph OH ÕH Ph (racemic) 4arrow_forwardThe oxymercuration/demercuration of the compound below will form what product? O a. 1-methycyclohexan-3-ol/1-methyl-3cyclohexanol O b. 1-methylcyclohexan-1-ol/1-methyl-1-cyclohexanol O c. 1-methylcyclohexan-2-ol/1-methyl-2-cyclohexanolarrow_forward
- 10. What products are formed when the following compound is treated with each reagent? If no reaction occurs, write NR. a. H₂/Pd b. K₂Cr2O7 c. Tollen's reagent d. 2 equiv. CH3OH, H+ e. 2 equiv. CH3CH₂OH, H+ f. Product of (e), then H₂O/H*arrow_forwardChoose the correct reagent (s) to perform the following transformation. Reagents for I [Select] Reagents for II [Select] To preview the image click here A. NaNH2 B. NaOEt C. NaOH A. B. H C. 1. OH 2. H3O+ 2. H3O+ HOarrow_forward2. What nucleophile could be used to produce each of the following products from 1- bromobutane? Identify the functional group introduced in each product. a. b. H;C CH3 CN H3C SH H3C N3 H3C e. d. CHarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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