Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
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Chapter 14, Problem 14.54SP
(a)
Interpretation Introduction
To determine: The number of ether groups in the given molecule.
Interpretation: The number of ether groups in the given molecule is to be identified.
Concept introduction: The ether group is represented by
(b)
Interpretation Introduction
To determine: The other oxygen-containing functional group in the given compound.
Interpretation: The other oxygen-containing functional group in the given compound is to be identified.
Concept introduction: The alcohol group is represented by
(c)
Interpretation Introduction
To determine: The number of atoms present in the large ring.
Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.
Concept introduction: Large ring contains large number of atoms called macrolide.
(d)
Interpretation Introduction
To determine: The number of chiral centres in the given molecule.
Interpretation: The number of chiral centres in the given molecule is to be identified.
Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.
(e)
Interpretation Introduction
To determine: The number of stereoisomers in the given molecule.
Interpretation: The number of stereoisomers in the given molecule is to be calculated.
Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.
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Students have asked these similar questions
1. Using Br2 in C2H4Br2 will result in HBr and ______.
a. C2H3Cl3
b. C2H4Cl3
c. C2H2Cl3
d. none of the above
2. How many halogenation are posible in propane?
a. 3
b. 8
c. 6
d. 10
3.Sulfonation of pentane will result in ________ and water.
a. C5H11SO3H
b. C5H12SO3H
c. C5H14SO3H
d. none of the above
4.Nitration of hexane will result in ________ and water.
a. C6H13SO3H
b. C6H15NO2
c. C6H13NO2
d. C6H14NO2
5.How many moles of O2 in heating a C12H26 (dodecane)
a. 27
b. 37
c. 24
d. none of the above
Consider the compounds 1-pentanol,CH3-CH2-CH2-CH2-CH2-OH, melting point -78C boiling point 138C, MW=88.15. 1,6-hexanediol ,HO-CH2-CH2-CH2-CH2-CH2-CH2-OH, mp 42C,bp=250C.MW=118.18. The compound 1,6-hexanediol is more soluble in water than 1-pentanol is. This is because 1,6-hexanediol....
1) has more carbon atoms
2)has a higher molecular weight
3)has more -OH groups
4)is a solid at room temperature
Phineas and Ferbs, two brothers who enjoy vacations, doing fun things every summer. This summer the brothers and their friends carry out an organic synthesis with an unknown compound (L1) that contains 52% Carbon, 6% Hydrogen and 42% bromine, this compound (L1) is treated with magnesium in ether to obtain L2 , which reacts violently with D2O for 1-methyl cyclohexene with a deuterium atom in the methyl group (L3). The L2 reaction is treated with acetone followed by hydrolysis to give L4. Heating L4 with concentrated sulfuric acid gives L5, which decolors the bromine, obtaining L6. L5 undergoes hydrogenation with excess hydrogen and platinum as a catalyst giving rise to isobutyl cyclohexane. Determine the structures of compounds L1 through L6.
Chapter 14 Solutions
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2PCh. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5PCh. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8PCh. 14.5 - Prob. 14.9PCh. 14.6 - Prob. 14.10P
Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
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